Kinetics of phase formation in solid - gas reactions: Iron and Arsenic
- Based on the experience of thermo-chemical studies on a High-Temperature Gas-Balance a time dependent analysis has been developed for the investigations of the kinetics of solid-gas reactions. The course of solid-gas reactions can be examined unambiguously by separation of the initial solids. By this setup the visualization of different stages of solid-gas reaction (vaporization, phase formation) becomes feasible. Time dependent analysis of the formation of FeAs results in an assignment of the underlying principles of kinetics derived from the conversion factor α.
Author: | Michael Schöneich, Peer SchmidtORCiD |
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URL: | http://onlinelibrary.wiley.com/doi/10.1002/zaac.201204026/full |
DOI: | https://doi.org/10.1002/zaac.201204026 |
Title of the source (German): | Zeitschrift für Anorganische und Allgemeine Chemie |
Document Type: | Scientific journal article peer-reviewed |
Language: | English |
Year of publication: | 2012 |
Tag: | Arsenic; High-temperature Gas-balance; Thermal analysis |
Volume/Year: | 638 |
Issue number: | 10 |
First Page: | S. 1579 |
Faculty/Chair: | Fakultät 2 Umwelt und Naturwissenschaften / FG Anorganische Chemie |