A spreader-bar approach to molecular architecture: formation of stable artificial chemoreceptors
- The destructive influence of lateral diffusion on nanostructured monolayers can be prevented by using the spreader-bar technique. This approach allows the formation of stable artificial receptors for barbituric acid by lateral structuring of a dodecanethiol monolayer with molecular spreader-bars from thiobarbituric acid without chemical polymerization (see schematic representation). The new technique may have applications in chemosensors, affinity chromatography, stereoselective catalysis, and molecular electronics.
Author: | Vladimir M. MirskyORCiDGND, Thomas Hirsch, Sergey A. Piletsky, Otto S. WolfbeisGND |
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DOI: | https://doi.org/10.1002/(SICI)1521-3773(19990419)38:8<1108::AID-ANIE1108>3.0.CO;2-C |
ISSN: | 1521-3773 |
Title of the source (English): | Angewandte Chemie International Edition |
Document Type: | Scientific journal article peer-reviewed |
Language: | English |
Year of publication: | 1999 |
Tag: | Molecular architecture; Molecular recognition; Monolayers; Nanostructures; Sensors |
Volume/Year: | 38 |
Issue number: | 8 |
First Page: | 1108 |
Last Page: | 1110 |
Faculty/Chair: | Fakultät 2 Umwelt und Naturwissenschaften / FG Nanobiotechnologie |