Synthesis and Identification of Metastable Compounds: Black Arsenic—Science or Fiction?

  • Back in black: All metastable and stable phases can be identified for the solid solution arsenic/phosphorus by a combination of quantum-chemical calculations and investigations of the phase formation. Reaction paths for phase formations and transitions in situ were also evaluated. The results show that orthorhombic black arsenic (o-As) is metastable in pure form and has only been previously obtained by stabilizing impurities.

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Author: Oliver Osters, Tom Nilges, Frederik BachhuberGND, Florian Pielnhofer, Richard Weihrich, Michael Schöneich, Peer SchmidtORCiD
URL:http://onlinelibrary.wiley.com/doi/10.1002/anie.201106479/abstract
DOI:https://doi.org/10.1002/anie.201106479
ISSN:1521-3773
Title of the source (English):Angewandte Chemie / International edition
Document Type:Scientific journal article peer-reviewed
Language:English
Year of publication:2012
Tag:arsenic; metastable phases; phase formation; phosphorus; solid-state structures
Volume/Year:51
Issue number:12
First Page:2994
Last Page:2997
Faculty/Chair:Fakultät 2 Umwelt und Naturwissenschaften / FG Anorganische Chemie
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