@misc{SproeteFischerVesteetal., author = {Spr{\"o}te, Roland and Fischer, Thomas and Veste, Maik and Raab, Thomas and Wiehe, Wolfgang and Lange, Philipp and Bens, Oliver and H{\"u}ttl, Reinhard F.}, title = {Biological topsoil crusts at early successional stages on recultivated post-mining sites in Brandenburg, NE Germany}, language = {en} } @inproceedings{SutLohmannRepmannFischeretal., author = {Sut-Lohmann, Magdalena and Repmann, Frank and Fischer, Thomas and Raab, Thomas}, title = {Retardation of iron-cyanide complexes in soils of a former Manufactured Gas Plant site}, series = {Book of abstracts, XII International Congress of Young Chemists, YoungChem2014, Szczecin, Poland 8th-12th October 2014}, booktitle = {Book of abstracts, XII International Congress of Young Chemists, YoungChem2014, Szczecin, Poland 8th-12th October 2014}, address = {Warsaw}, isbn = {978-83-61037-28-6}, pages = {S. 44}, language = {en} } @misc{BonhageMykhailovaHirschetal., author = {Bonhage, Alexander and Mykhailova, Larysa and Hirsch, Florian and Schneider, Anna and Raab, Thomas and Fischer, Thomas and Raab, Alexandra and Donovan, Sally and Ouimet, William}, title = {Effects of historical charcoal burning on soil landscapes in West Connecticut - Quantifying pyrogenic and organic soil carbon content of Technosols by FTIR analysis}, series = {European Geosciences Union, General Assembly 2019, Vienna, Austria, 7-12 April 2019}, journal = {European Geosciences Union, General Assembly 2019, Vienna, Austria, 7-12 April 2019}, address = {Katlenburg-Lindau}, language = {en} } @misc{BonhageRaabSchneideretal., author = {Bonhage, Alexander and Raab, Thomas and Schneider, Anna and Fischer, Thomas and Ramezany, Shaghayegh and Ouimet, William and Raab, Alexandra and Hirsch, Florian}, title = {Vertical SOC distribution and aromatic carbon in centuries old charcoal-rich Technosols}, series = {European Journal of Soil Science}, volume = {73}, journal = {European Journal of Soil Science}, number = {4}, doi = {10.1111/ejss.13293}, pages = {1 -- 16}, abstract = {Charcoal-rich Technosols on century-old relict charcoal hearths (RCHs) are the subject of ongoing research regarding potential legacy effects that result from historic charcoal production and subsequent charcoal amendments on forest soil properties and forest ecosystems today. RCHs consist mostly of Auh horizons that are substantially enriched in soil organic carbon (SOC), of which the largest part seems to be of pyrogenic origin (PyC). However, the reported range of SOC and PyC contents in RCH soil also suggests that they are enriched in nonpyrogenic SOC. RCH soils are discussed as potential benchmarks for the long-term influence of biochar amendment and the post-wildfire influences on soil properties. In this study, we utilised a large soil sample dataset (n = 1245) from 52 RCH sites in north-western Connecticut, USA, to quantify SOC contents by total element analysis. The contents of condensed highly aromatic carbon as a proxy for black carbon (BC) were predicted by using a modified benzene polycarboxylated acid (BPCA) marker method in combination with diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy-based partial least square regression (r2 = 0.89). A high vertical spatial sampling resolution allowed the identification of soil organic matter (SOM) enrichment and translocation processes. The results show an average 75\% and 1862\% increase in TOC and BPCA-derived carbon, respectively, for technogenic Auh horizons compared to reference soils. In addition to an increase in aromatic properties, increased carboxylic properties of the RCH SOC suggest self-humification effects of degrading charcoal and thereby the continuing formation of leachable aromatic carbon compounds, which could have effects on pedogenic processes in buried soils. Indeed, we show BPCA-derived carbon concentrations in intermediate technogenic Cu horizons and buried top/subsoils that suggest vertical translocation of highly aromatic carbon originating in RCH Auh horizons. Topmost Auh horizons showed a gradual decrease in total organic carbon (TOC) contents with increasing depth, suggesting accumulation of recent, non-pyrogenic SOM. Lower aliphatic absorptions in RCH soil spectra suggest different SOM turnover dynamics compared to reference soils. Furthermore, studied RCH soils featured additional TOC enrichment, which cannot be fully explained now.}, language = {en} } @misc{PreusserBroeringFischeretal., author = {Preußer, Daniel and Br{\"o}ring, Udo and Fischer, Thomas and Juretzek, Thomas}, title = {Effects of antibiotics ceftriaxone and levofloxacin on the growth of Calliphora vomitoria L. (Diptera: Calliphoridae) and effects on the determination of the post-mortem interval}, series = {Journal of Forensic and Legal Medicine}, volume = {81}, journal = {Journal of Forensic and Legal Medicine}, number = {5}, issn = {1878-7487}, doi = {10.1016/j.jflm.2021.102207}, abstract = {The determination of the post-mortem interval (PMI) is one of the main tasks of forensic entomology, where growth and stages of development of arthropods are used for PMI determination. It is well acknowledged that maggot development is significantly influenced by temperature. Attention has also been paid to the microbial populations of the cadaver, because toxic substances contained in the substrate can influence the microorganisms and affect arthropods growth and development. However, little is known about the influence of antibiotics taken during lifetime of a person on insect development after that persons death. The aim of this study was to test the hypothesis that the antibiotics ceftriaxone and levofloxacin cause inhibition of growth and delay of pupation of the blow fly Calliphora vomitoria, which would then lead to an incorrect determination of the post-mortem interval in forensic cases. It was found that maggot development was delayed by levofloxacin mixed in minced pork, where a mixture of both antibiotics increased this effect. The maggot growth in the samples with ceftriaxone was not delayed. Pupation was delayed in treatments with a mixture of both antibiotics. The mortality was reduced by separate or combined application of ceftriaxone and levofloxacin, which we attribute to a bactericidal effect of the antibiotics on maggot pathogens. Depending on the concentration of the antibiotics, an underestimation of the post-mortem interval between 24 and 48 h could be suspected. We conclude that antibiotics need to be considered if instar stages are to be used to determine the PMI and that some antibiotics may improve the breeding conditions of maggots.}, language = {en} } @inproceedings{SproeteVesteFischeretal., author = {Spr{\"o}te, Roland and Veste, Maik and Fischer, Thomas and Raab, Thomas and Bens, Oliver and H{\"u}ttl, Reinhard F.}, title = {Development of biological soil crusts and their influence on soil hydrology in the recultivation area of lignite open-cast mining district in Lower Lusatia (Germany)}, series = {EGU General Assembly 2012, held 22-27 April, 2012 in Vienna}, booktitle = {EGU General Assembly 2012, held 22-27 April, 2012 in Vienna}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @inproceedings{SproeteVesteFischeretal., author = {Spr{\"o}te, Roland and Veste, Maik and Fischer, Thomas and Lange, Philipp and Bens, Oliver and Raab, Thomas and H{\"u}ttl, Reinhard F.}, title = {Wie beeinflussen Kiefern (Pinus sylvestris L.) die Entwicklung der Benetzungshemmung auf Sandb{\"o}den?}, series = {B{\"o}den verstehen - B{\"o}den nutzen - B{\"o}den fit machen, Jahrestagung der Deutschen Bodenkundlichen Gesellschaft, 3. - 9. September 2011}, booktitle = {B{\"o}den verstehen - B{\"o}den nutzen - B{\"o}den fit machen, Jahrestagung der Deutschen Bodenkundlichen Gesellschaft, 3. - 9. September 2011}, language = {de} } @misc{ElmerBachmannGutschetal., author = {Elmer, Michael and Bachmann, Ute and Gutsch, Martin and Schr{\"o}der, Jens and B{\"a}ucker, Ernst and Lange, Mike and Clauder, Lothar and Bens, Oliver and Suckow, Felicitas and K{\"a}tzel, Ralf and Bues, Claus-Thomas and Frommhold, Heinz and Sonntag, Herbert and Fischer, Thomas and H{\"u}ttl, Reinhard F.}, title = {OakChain: Eichen-Kiefern-Mischbest{\"a}nde im Spannungsfeld von Klimawandel, Waldumbau und internationalem Holzmarkt}, series = {Forst und Holz}, volume = {64}, journal = {Forst und Holz}, number = {7/8}, issn = {0932-9315}, pages = {26 -- 29}, language = {de} } @inproceedings{SproeteBensFischeretal., author = {Spr{\"o}te, Roland and Bens, Oliver and Fischer, Thomas and Raab, Thomas and H{\"u}ttl, Reinhard F.}, title = {Soil water repellency as a phenomenon of initial soil formation - approaches and first results from the Transregional Collaborative Reserch Centre (SFB/TRR) 38}, series = {EGU General Assembly 2009, held in Vienna, Austria, 19 - 24 April 2009}, booktitle = {EGU General Assembly 2009, held in Vienna, Austria, 19 - 24 April 2009}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @incollection{BachmannBensElmeretal., author = {Bachmann, Ute and Bens, Oliver and Elmer, Michael and Fischer, Thomas and Raab, Thomas and H{\"u}ttl, Reinhard F.}, title = {Boden und Standortqualit{\"a}t}, series = {Nachhaltige Bewirtschaftung von Eichen-Kiefern-Mischbest{\"a}nden : im Spannungsfeld von Klimawandel, Waldumbau und internationalem Holzmarkt}, booktitle = {Nachhaltige Bewirtschaftung von Eichen-Kiefern-Mischbest{\"a}nden : im Spannungsfeld von Klimawandel, Waldumbau und internationalem Holzmarkt}, editor = {Elmer, Michael and K{\"a}tzel, Ralf and Bens, Oliver and Bues, Claus-Thomas and Sonntag, Herbert and H{\"u}ttl, Reinhard F.}, publisher = {oekom}, address = {M{\"u}nchen}, isbn = {978-3-86581-196-7}, pages = {31 -- 44}, language = {de} } @inproceedings{SproeteVesteFischeretal., author = {Spr{\"o}te, Roland and Veste, Maik and Fischer, Thomas and Lange, Philipp and Bens, Oliver and Raab, Thomas and H{\"u}ttl, Reinhard F.}, title = {Development of biologicalsoil crusts in initial ecosystems in Lusatia, Germany}, series = {DBG Jahrestagung 2009 Bonn "B{\"o}den - eine endliche Ressource", 05.-13.09.2009, Bonn}, booktitle = {DBG Jahrestagung 2009 Bonn "B{\"o}den - eine endliche Ressource", 05.-13.09.2009, Bonn}, language = {en} } @inproceedings{SutLohmannFischerRepmannetal., author = {Sut-Lohmann, Magdalena and Fischer, Thomas and Repmann, Frank and Raab, Thomas}, title = {Feasibility of field portable near infrared (NIR) spectroscopy to determine cyanide concentrations in soil}, series = {European Geosciences Union, General Assembly 2013, Vienna, Austria, 07 - 12 April 2013}, booktitle = {European Geosciences Union, General Assembly 2013, Vienna, Austria, 07 - 12 April 2013}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {In Germany, at more than 1000 sites, soil is polluted with an anthropogenic contaminant in form of iron-cyanide complexes. These contaminations are caused by former Manufactured Gas Plants (MGPs), where electricity for lighting was produced in the process of coal gasification. The production of manufactured gas was restrained in 1950, which caused cessation of MGPs. Our study describes the application of Polychromix Handheld Field Portable Near-Infrared (NIR) Analyzer to predict the cyanide concentrations in soil. In recent times, when the soil remediation is of major importance, there is a need to develop rapid and non-destructive methods for contaminant determination in the field. In situ analysis enables determination of 'hot spots', is cheap and time saving in comparison to laboratory methods. This paper presents a novel usage of NIR spectroscopy, where a calibration model was developed, using multivariate calibration algorithms, in order to determine NIR spectral response to the cyanide concentration in soil samples. As a control, the contaminant concentration was determined using conventional Flow Injection Analysis (FIA). The experiments revealed that portable near-infrared spectrometers could be a reliable device for identification of contamination 'hot spots', where cyanide concentration are higher than 2400 mg kg-1 in the field and >1750 mg kg-1 after sample preparation in the laboratory, but cannot replace traditional laboratory analyses due to high limits of detection.}, language = {en} } @inproceedings{FischerSproeteVesteetal., author = {Fischer, Thomas and Spr{\"o}te, Roland and Veste, Maik and Wiehe, Wolfgang and Lange, Philipp and Bens, Oliver and Raab, Thomas and H{\"u}ttl, Reinhard F.}, title = {Functions of biological soil crusts on central European inland dunes:Water repellency and pore clogging influence water infiltration}, series = {EGU General Assembly 2010, held in Vienna, Austria, 02 - 07 May 2010}, booktitle = {EGU General Assembly 2010, held in Vienna, Austria, 02 - 07 May 2010}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @inproceedings{SproeteFischerVesteetal., author = {Spr{\"o}te, Roland and Fischer, Thomas and Veste, Maik and Lange, Philipp and Bens, Oliver and Raab, Thomas and H{\"u}ttl, Reinhard F.}, title = {Hydrophobicity in sandy soils triggered by the development of Scots Pine stands in southern Brandenburg, Germany}, series = {EGU General Assembly 2010, held in Vienna, Austria, 02 - 07 May 2010}, booktitle = {EGU General Assembly 2010, held in Vienna, Austria, 02 - 07 May 2010}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @misc{PreusserFischerJuretzek, author = {Preußer, Daniel and Fischer, Thomas and Juretzek, Thomas}, title = {Effects of antibiotics ceftriaxone and levofloxacin on the growth of Lucilia sericata (Diptera: Calliphoridae)}, series = {Medical and Veterinary Entomology}, volume = {37}, journal = {Medical and Veterinary Entomology}, number = {4}, issn = {0269-283X}, doi = {10.1111/mve.12685}, pages = {805 -- 815}, abstract = {Lucilia sericata is one of the most studied species in forensic entomology due to its widespread distribution, forensic importance as well as medical use. The growth and development stage of maggots is often used to determine the post-mortem interval in forensic cases. L. sericata can cause myiasis in humans who are not able to maintain personal hygiene due to age or medical condition and can therefore be used to determine the time period of neglect. The influence of the temperature on the maggot development has been examined in various studies. Different examinations on the effects of toxic substances on the maggot development and survival have been conducted in order to test the influence and resulting deviations. In this study, the effects of different therapeutical doses of the antibiotics ceftriaxone and levofloxacin were examined on L. sericata in order to determine and compare deviations in maggot development and survival. The used antibiotics did not significantly influence the maggot weight and length. A significant delay in the time of pupation has been determined in the treatments with high concentrations of levofloxacin. The mortality was significantly increased in all treatments with antibiotics compared to the control, whereby the survivability of all treatments remained over 80\%. Because of the high doses needed to produce an effect, we concluded that an overestimation of the post-mortem interval is unlikely but higher antibiotic concentrations or possible interactions with other medications could increase the maggot development time.}, language = {en} } @misc{SutLohmannFischerRepmannetal., author = {Sut-Lohmann, Magdalena and Fischer, Thomas and Repmann, Frank and Raab, Thomas and Dimitrova, Tsvetelina}, title = {Feasibility of field portable near infrared (NIR) spectroscopy to determine cyanide concentrations in soil}, series = {Water, Air and Soil Pollution}, volume = {223}, journal = {Water, Air and Soil Pollution}, number = {8}, issn = {1573-2932}, doi = {10.1007/s11270-012-1298-y}, pages = {5495 -- 5504}, abstract = {Vicinities of manufactured gas plants were often contaminated with solid iron-cyanide complexes as a result of the coal gasification process. During the remediation of affected soils, knowledge about contaminant concentrations is crucial, but laboratory methods are often expensive and time consuming. Rapid and non-destructive field methods for contaminant determination permit an analysis of large sample numbers and hence, facilitate identification of 'hot spots' of contamination. Diffuse near infrared reflectance spectroscopy has proven to be a reliable analytical tool in soil investigation. In order to determine the feasibility of a Polychromix Handheld Field Portable Near-Infrared Analyzer (FP NIR), various sample preparation methods were examined, including homogenizing, sieving, drying, and grinding. Partial least squares calibration models were developed to determine near infrared (NIR) spectral responses to the cyanide concentration in the soil samples. As a control, the contaminant concentration was determined using conventional flow injection analysis. The experiments revealed that portable near-infrared spectrometers could be a reliable device for detecting cyanide concentrations >2,400 mgkg-1 in the field and >1,750 mgkg-1 after sample preparation in the laboratory.We found that portable NIR spectrometry cannot replace traditional laboratory analyses due to high limits of detection, but that it could be used for identification of contamination 'hot spots'.}, language = {en} } @misc{SproeteFischerVesteetal., author = {Spr{\"o}te, Roland and Fischer, Thomas and Veste, Maik and Raab, Thomas and Wiehe, Wolfgang and Lange, Philipp and Bens, Oliver and H{\"u}ttl, Reinhard F.}, title = {Biological topsoil crusts at early successional stages on Quaternary substrates dumped by mining in Brandenburg, NE Germany}, series = {Geomorphologie: relief, processus, environnement}, volume = {16}, journal = {Geomorphologie: relief, processus, environnement}, number = {4}, issn = {1957-777X}, doi = {10.4000/geomorphologie.8083}, pages = {359 -- 370}, abstract = {The influence of biological soil crusts in natural ecosystems on structures and processes is well investigated. However, in South-Brandenburg (Germany), it is possible to study the development of biological soil crusts (BSC) during initial ecosystem genesis on two artificial water catchments with well-known ages and under differing starting conditions. The two experimental sites are located in the recultivation area of the lignite open-cast mining district of southern Brandenburg with a distance of approximately 1 km between them. Two different topographies were constructed at the experimental sites: the experimental plot at the catchment Neuer Lugteich was shaped like a dune, whereas the artificial water catchment H{\"u}hnerwasser was modelled as an inclined slope. The catchment Neuer Lugteich is four years older than H{\"u}hnerwasser. The original substrate at Neuer Lugteich is more sandy and carbonate-free compared to the original substrate dumped at H{\"u}hnerwasser. At both sites geomorphological differentiation and crust development were compared and the importance of substrate-dependent water availability and crust type clarified. Once settled, the crusts influenced the water regime of the soils by delaying infiltration through enhanced water repellency, and by limiting water infiltration. Chlorophyll analysis revealed that all crusts were at early stages of development. At Neuer Lugteich, the establishment of the biological soil crusts was closely associated with the vegetation succession, whereas no clear succession of the crusts could be observed at H{\"u}hnerwasser. The mosaic-like pattern of the biological soils crusts is associated with the distribution of fine-grained material here.zeige weniger}, language = {en} } @misc{SutLohmannFischerRepmannetal., author = {Sut-Lohmann, Magdalena and Fischer, Thomas and Repmann, Frank and Raab, Thomas}, title = {Long-Term Release of Iron-Cyanide Complexes from the Soil of a Manufactured Gas Plant Site}, series = {Journal of Environmental Protection}, volume = {4}, journal = {Journal of Environmental Protection}, number = {11B}, issn = {2152-2219}, doi = {10.4236/jep.2013.411A2002}, pages = {8 -- 19}, abstract = {Iron-cyanide (Fe-CN) complexes have been detected at Manufactured Gas Plant sites (MGP) worldwide. The risk of groundwater contamination depends mainly on the dissolution of ferric ferrocyanide. In order to design effective reme- diation strategies, it is relevant to understand the contaminant's fate and transport in soil, and to quantify and mathe- matically model a release rate. The release of iron-cyanide complexes from four contaminated soils, originating from the former MGP in Cottbus, has been studied by using a column experiment. Results indicated that long-term cyanide (CN) release is governed by two phases: one readily dissolved and one strongly fixed. Different isotherm and kinetic equations were used to investigate the driving mechanisms for the ferric ferrocyanide release. Applying the isotherm equations assumed an approach by which two phases were separate in time, whereas the multiple first order equation considered simultaneous occurrence of both cyanide pools. Results indicated varying CN release rates according to the phase and soil. According to isotherm and kinetic models, the long-term iron cyanide release from the MGP soils is a complex phenomenon driven by various mechanisms parallely involving desorption, diffusion and transport processes. Phase I (rapid release) is presumably mainly constrained by the transport process of readily dissolved iron-cyanide complexes combined with desorption of CN bound to reactive heterogeneous surfaces that are in direct contact with the aqueous phase (outer-sphere complexation). Phase II (limited rate) is presumably driven by the diffusion controlled processes involving dissolution of precipitated ferric ferrocyanide from the mineral or inner-sphere complexation of fer- ricyanides. CN release rates in phase I and II were mainly influenced by the pH, organic matter (OM) and the total CN content. The cyanide release rates increased with increasing pH, decreased with low initial CN concentration and were retarded by the increase in OM content.}, language = {en} } @misc{RodionovNiiAnnangFischeretal., author = {Rodionov, Andrei and Nii-Annang, Seth and Fischer, Thomas and Gattinger, Andreas and Bens, Oliver and Raab, Thomas and H{\"u}ttl, Reinhard F.}, title = {Cross-linked polyacrylates in post-mining substrates: persistence and effects on plant growth}, series = {Soil Use and Management}, volume = {30}, journal = {Soil Use and Management}, number = {1}, issn = {1475-2743}, doi = {10.1111/sum.12103}, pages = {78 -- 87}, abstract = {Application of hydrophilic polymers composed of cross-linked polyacrylate can improve soil water-holding capacity and accelerate the restoration of post-mining substrates. In this work, we studied the persistence of a polyacrylate polymer incorporated into a soil and its impact on plant nutrients at a reclamation site of former lignite mining in Lusatia (Germany). In contrast to autumn application, the incorporation of the polymer enhanced the sequestration of plant-derived carbon in the soil, which was reflected by a significant increase in the concentration of a lignin marker. Attenuated total reflexion-Fourier transform infrared spectra (ATR-FTIR) and total elemental contents in the applied polymer suggested an intensive cation exchange between the polymer framework and the soil-forming substrate. In addition, there was an enrichment of carbonaceous material, which seems to reduce the swelling and thus the water-holding capacity of the cross-linked polyacrylate. Conversely, this process protected the polymer structure from rapid decomposition.}, language = {en} } @misc{HirschSproeteFischeretal., author = {Hirsch, Florian and Spr{\"o}te, Roland and Fischer, Thomas and Forman, Steven L. and Raab, Thomas and Bens, Oliver and H{\"u}ttl, Reinhard F.}, title = {Late Quaternary aeloian dynamics, pedostratigraphy and soil formation in the North European Lowlands - new findings from the Baruther ice-marginal valley}, series = {Die Erde}, volume = {148}, journal = {Die Erde}, number = {1}, issn = {0013-9998}, doi = {10.12854/erde-148-30}, pages = {58 -- 73}, abstract = {The formation of dunes in central Europe reflects ample sediment supply during the last deglacial hemicycle. A Quaternary inland dune complex in southern Brandenburg, Germany, was studied to frame the duration of pedogenesis in two outcrops containing buried paleosols. An integrative approach, which combined geomorphological, sedimentological, pedological and chronological methods was used to identify aeolian deposition events, ensuing pedogenesis and anthropogenic remobilization. At the outcrops, which were situated approximately 2 km apart from each other, a total of twelve samples of the aeolian sands were dated using optically stimulated luminescence (OSL) and a further six samples using 14C dating. Although the dunes have similar morphological features, these forms have a different history of aeolian sand deposition and pedogenesis. At the older dune (Gl 1) the surface soil is a well developed Podzol, whereas soil development of the younger dune (Gl 2) is clearly in an initial state. The studied sites of the dune complex also differ in grain size distribution and in the presence of buried soils, thereby indicating a climatic impact on aeolian remobilization.}, language = {en} } @inproceedings{MykhailovaRaabGypseretal., author = {Mykhailova, Larysa and Raab, Thomas and Gypser, Stella and Fischer, Thomas}, title = {Development and hydrology of biological soil crusts -- first results from a surface inoculation experiment}, series = {European Geosciences Union, General Assembly 2016, Vienna, Austria, 17 April - 22 May 2016}, booktitle = {European Geosciences Union, General Assembly 2016, Vienna, Austria, 17 April - 22 May 2016}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @inproceedings{SproeteFischerVesteetal., author = {Spr{\"o}te, Roland and Fischer, Thomas and Veste, Maik and Yair, Aaron and Wiehe, Wolfgang and Lange, Philipp and Bens, Oliver and Raab, Thomas and H{\"u}ttl, Reinhard F.}, title = {Structures and processes of biological soil crusts during initial ecosystem genesis of an artificial watershed in Lusatia, NE Germany}, series = {EGU General Assembly 2010, held Vienna, Austria, 02 - 07 May 2010}, booktitle = {EGU General Assembly 2010, held Vienna, Austria, 02 - 07 May 2010}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @misc{PreusserFischerJuretzek, author = {Preußer, Daniel and Fischer, Thomas and Juretzek, Thomas}, title = {Effects of antibiotics ceftriaxone and levofloxacin on the growth of Protophormia terraenovae (Diptera: Calliphoridae)}, series = {Forensic Science, Medicine and Pathology}, journal = {Forensic Science, Medicine and Pathology}, issn = {1556-2891}, doi = {10.1007/s12024-024-00804-9}, pages = {1 -- 13}, abstract = {AbstractProtophormia terraenovae is a colonizer of decomposing bodies and is known to cause pre-mortem myiasis as the female flies lay eggs in uncleaned wounds. In this study the effects of different concentrations of antibiotics levofloxacin and ceftriaxone on maggot development, weight, length, and mortality were examined. The maggot length and weight were significantly increased by therapeutical doses of levofloxacin and ceftriaxone. The maggot development time was significantly decreased in every levofloxacin treatment compared to the control. The time to start pupation was significantly increased in the control compared to the antibiotic treatments. Levofloxacin significantly increased the survivability of the maggots. Every levofloxacin treatment significantly improved the rearing conditions for the maggots. Reaching the third instar was delayed by 24 h in the control compared to the Levo 3.57 treatment. The Pupation in the control was delayed by an average of 48 h compared to the Levo 3.57 treatment. The significantly reduced development time of the maggots in the antibiotic treatments might lead to an overestimation of the post-mortem interval and therefore an incorrect time of death determination. The improved rearing conditions may be an indication of the potential of a combined application of antibiotics and maggot therapy.}, language = {en} } @misc{FischerBergmannHuettl, author = {Fischer, Thomas and Bergmann, Charlotte and H{\"u}ttl, Reinhard F.}, title = {Soil carbon and nitrogen budget in Scots pine (Pinus sylvestris L) stands along an air pollution gradient in Eastern Germany}, language = {en} } @misc{BergmannFischerHuettl, author = {Bergmann, Charlotte and Fischer, Thomas and H{\"u}ttl, Reinhard F.}, title = {Significance of litter- and humus-layer quality for rates and forms of N cycling in moder- to rawhumus-moder profiles under Scots pine (Pinus sylvestris L.)}, language = {en} } @misc{Fischer, author = {Fischer, Thomas}, title = {Substantial rewetting phenomena on soil respiration can be observed at low water availability}, language = {en} } @misc{FischerVesteWieheetal., author = {Fischer, Thomas and Veste, Maik and Wiehe, Wolfgang and Lange, Philipp}, title = {Water repellency and pore clogging at early successional stages of microbiotic crusts on inland dunes, Brandenburg, NE Germany}, language = {en} } @inproceedings{Fischer, author = {Fischer, Thomas}, title = {Following chemical changes of Scots pine (Pinus sylvestris L.) root litter during decomposition using FTIR}, series = {Woody root processes - Impact of different tree species, University of Tartu, Estonia, 05-09 June 2005}, booktitle = {Woody root processes - Impact of different tree species, University of Tartu, Estonia, 05-09 June 2005}, publisher = {Tartu University Press}, address = {Tartu}, isbn = {9949-11-079-3}, pages = {21}, language = {en} } @misc{Fischer, author = {Fischer, Thomas}, title = {Einfluß ausgew{\"a}hlter Fruchtfolgen und Fruchtarten auf die Kohlenstoffdynamik des Bodens auf einem grundwasserfernen Sandstandort}, series = {Mitteilungen der Gesellschaft f{\"u}r Pflanzenbauwissenschaften}, volume = {4}, journal = {Mitteilungen der Gesellschaft f{\"u}r Pflanzenbauwissenschaften}, issn = {0934-5116}, pages = {339 -- 342}, language = {de} } @misc{Fischer, author = {Fischer, Thomas}, title = {Einfluß von Winterweizen und Winterroggen in Fruchtfolgen mit unterschiedlichem Getreideanteil auf die mikrobielle Biomasse und die jahreszeitliche Kohlenstoffdynamik des Bodens}, series = {Archiv f{\"u}r Acker- und Pflanzenbau und Bodenkunde}, volume = {37}, journal = {Archiv f{\"u}r Acker- und Pflanzenbau und Bodenkunde}, issn = {0365-0340}, pages = {181 -- 189}, language = {de} } @incollection{Fischer, author = {Fischer, Thomas}, title = {Auswirkungen einer Wiederbefeuchtung auf die C- und N-Mineralisierung in der Humusauflage von Kiefern{\"o}kosystemen}, series = {Pflanzliche Stoffaufnahme und mikrobielle Wechselwirkungen in der Rhizosphere}, booktitle = {Pflanzliche Stoffaufnahme und mikrobielle Wechselwirkungen in der Rhizosphere}, editor = {Merbach, Wolfgang}, publisher = {Teubner}, address = {Stuttgart [u.a.]}, isbn = {3-8154-3528-5}, pages = {13 -- 20}, language = {de} } @inproceedings{FischerYairVeste, author = {Fischer, Thomas and Yair, Aaron and Veste, Maik}, title = {Infiltration, water holding capacity and growth patterns of biological soil crusts on sand dunes under arid and temperate climates}, series = {EGU General Assembly 2012, held 22-27 April, 2012 in Vienna}, booktitle = {EGU General Assembly 2012, held 22-27 April, 2012 in Vienna}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {de} } @misc{DolezychFischerGroeschke, author = {Dolezych, Martina and Fischer, Thomas and Gr{\"o}schke, Andreas}, title = {Pinuxylon succiniferum (GOEPPERT) KRAEUSEL emend. DOLEZYCH - amberized wood from GOEPPERT}, series = {Mauritiana}, volume = {22}, journal = {Mauritiana}, issn = {0233-173X}, pages = {43 -- 60}, language = {en} } @inproceedings{FischerVeste, author = {Fischer, Thomas and Veste, Maik}, title = {Small scale spatial heterogeneity of biological soil crusts during initial ecosystem development}, series = {Abstract Book of the 12th European Ecological Federation Congress, 25-29 September 2011, Avila, Spain}, booktitle = {Abstract Book of the 12th European Ecological Federation Congress, 25-29 September 2011, Avila, Spain}, pages = {S. 250}, language = {en} } @inproceedings{FischerVeste, author = {Fischer, Thomas and Veste, Maik}, title = {Biological soil crusts on inland dunes in NE Germany: Can we link succession with hydrology?}, series = {Book of Abstracts Workshop "Biological Soil Crusts in Ecosystems - their Diversity, Ecology, and Management", 22-25. August 2010, Zellingen-Retzbach, Germany}, booktitle = {Book of Abstracts Workshop "Biological Soil Crusts in Ecosystems - their Diversity, Ecology, and Management", 22-25. August 2010, Zellingen-Retzbach, Germany}, pages = {S. 52}, language = {en} } @misc{GeppertFischer, author = {Geppert, Helmut and Fischer, Thomas}, title = {CHROMATOGRAPHIE-Festphasenmikroextraktion von polaren Verbindungen}, series = {Labor Praxis}, volume = {33}, journal = {Labor Praxis}, number = {1}, issn = {0344-1733}, pages = {46 -- 47}, language = {de} } @inproceedings{FischerVesteLangeetal., author = {Fischer, Thomas and Veste, Maik and Lange, Philipp and Wiehe, Wolfgang}, title = {How biological soil crusts are stabilizing the soil surface? The development of organo-mineral interactions in the initial phase}, series = {EGU General Assembly 2009, held in Vienna, Austria, 19 - 24 April 2009}, booktitle = {EGU General Assembly 2009, held in Vienna, Austria, 19 - 24 April 2009}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @misc{FischerVesteBensetal., author = {Fischer, Thomas and Veste, Maik and Bens, Oliver and H{\"u}ttl, Reinhard F.}, title = {Dew formation on the surface of biological soil crusts in central European sand ecosystems}, series = {Biogeosciences}, volume = {9}, journal = {Biogeosciences}, issn = {1726-4189}, doi = {10.5194/bg-9-4621-2012}, pages = {4621 -- 4628}, abstract = {Dew formation was investigated in three developmental stages of biological soil crusts (BSC), which were collected along a catena of an inland dune and in the initial substrate. The Penman equation, which was developed for saturated surfaces, was modified for unsaturated surfaces and used for prediction of dewfall rates. The levels of surface saturation required for this approach were predicted using the water retention functions and the thicknesses of the BSCs. During a first field campaign (2-3 August 2011), dewfall increased from 0.042 kg m-2 for the initial sandy substrate to 0.058, 0.143 and 0.178 kg m-2 for crusts 1 to 3, respectively. During a second field campaign (17-18 August 2011), where dew formation was recorded in 1.5 to 2.75-h intervals after installation at 21:30 CEST, dewfall increased from 0.011 kg m-2 for the initial sandy substrate to 0.013, 0.028 and 0.055 kg m-2 for crusts 1 to 3, respectively. Dewfall rates remained on low levels for the substrate and for crust 1, and decreased overnight for crusts 2 and 3 (with crust 3 > crust 2 > crust 1 throughout the campaign). Dew formation was well reflected by the model response. The suggested mechanism of dew formation involves a delay in water saturation in near-surface soil pores and extracellular polymeric substances (EPS) where the crusts were thicker and where the water capacity was high, resulting in elevated vapor flux towards the surface. The results also indicate that the amount of dewfall was too low to saturate the BSCs and to observe water flow into deeper soil. Analysis of the soil water retention curves revealed that, despite the sandy mineral matrix, moist crusts clogged by swollen EPS pores exhibited a clay-like behavior. It is hypothesized that BSCs gain double benefit from suppressing their competitors by runoff generation and from improving their water supply by dew collection. Despite higher amounts of dew, the water availability to the crust community decreases with crust development, which may be compensated by ecophysiological adaptation of crust organisms, and which may further suppress higher vegetation or mosses.}, language = {en} } @misc{BrankatschkFischerVesteetal., author = {Brankatschk, Robert and Fischer, Thomas and Veste, Maik and Zeyer, Josef}, title = {Succession of N Cycling Processes in Biological Soil Crusts on a Central European Inland Dune}, series = {FEMS Microbiology Ecology}, volume = {83}, journal = {FEMS Microbiology Ecology}, number = {1}, issn = {1574-6941}, doi = {10.1111/j.1574-6941.2012.01459.x}, pages = {149 -- 160}, abstract = {Biological soil crusts (BSCs) are microbial assemblages that occur worldwide and facilitate ecosystem development by nitrogen (N) and carbon accumulation. N turnover within BSC ecosystems has been intensively studied in the past; however, shifts in the N cycle during BSC development have not been previously investigated. Our aim was to characterise N cycle development first by the abundance of the corresponding functional genes (in brackets) and second by potential enzyme activities; we focussed on the four processes: N fixation (nifH), mineralisation as proteolysis and chitinolysis (chiA), nitrification (amoA) and denitrification (nosZ). We sampled from four phases of BSC development and from a reference located in the rooting zone of Corynephorus canescens, on an inland dune in Germany. BSC development was associated with increasing amounts of chlorophyll, organic carbon and N. Potential activities increased and were highest in developed BSCs. Similarly, the abundance of functional genes increased. We propose and discuss three stages of N process succession. First, the heterotrophic stage (mobile sand without BSCs) is dominated by mineralisation activity. Second, during the transition stage (initial BSCs), N accumulates, and potential nitrification and denitrification activity increases. Third, the developed stage (established BSCs and reference) is characterised by the dominance of nitrification.}, language = {de} } @misc{XiaoWangFanetal., author = {Xiao, Bo and Wang, Huifang and Fan, Jun and Fischer, Thomas and Veste, Maik}, title = {Biological soil crusts decrease soil temperature in summer and increase soil temperature in winter in semiarid environment}, series = {Ecological Engineering}, volume = {58}, journal = {Ecological Engineering}, issn = {0925-8574}, doi = {10.1016/j.ecoleng.2013.06.009}, pages = {52 -- 56}, abstract = {In hot and wet conditions in summer, the biological soil crusts (BSCs) decreased soil temperature by up to 11.8 °C, 7.5 °C, 5.4 °C, and 3.2 °C at surface, 5 cm, 15 cm, and 30 cm, respectively; while in cold and dry conditions in winter the BSCs increased soil temperature by up to 1.2 °C, 1.2 °C, and 1.1 °C at 5 cm, 15 cm, and 30 cm, respectively. The daily mean soil temperatures of the BSCs in a whole year were averagely increased by 0.57 ± 0.04 °C, 0.31 ± 0.04 °C, and 0.22 ± 0.04 °C at 5 cm, 15 cm, and 30 cm, respectively. The effects of the BSCs on soil temperature were positively correlated with air temperature and soil moisture, and decreased with soil depth from surface to deep soil. We concluded that BSCs relieved the extreme hot and cold soil micro-environments in desert ecosystem to some extent. Therefore their effects on soil temperature are positive for improving water and nutrient availability and biological community structure, thus decreasing susceptibility to desertification. These results would be helpful for understanding the ecological and hydrological functions of BSCs in semiarid environment.}, language = {en} } @misc{FischerYairVesteetal., author = {Fischer, Thomas and Yair, Aaron and Veste, Maik and Geppert, Helmut}, title = {Hydraulic properties of biological soil crusts on sand dunes studied by 13C-CP/MAS-NMR: a comparison between an arid and a temperate site}, series = {Catena}, volume = {110}, journal = {Catena}, issn = {0341-8162}, doi = {10.1016/j.catena.2013.06.002}, pages = {155 -- 160}, abstract = {Using principal component analysis (PCA), we studied the relationships between hydraulic properties and 13C-CP/MAS-NMR shift regions of biological soil crusts (BSCs) on sand dunes under arid and temperate conditions. The arid study site was located near Nizzana, in the northwestern Negev, Israel and the temperate site was near Lieberose, Brandenburg, Germany. BSCs were sampled at each site near the dune crest, at the center of the dune slope and at the dune base. The soil texture was finer and water holding capacities (WHCs) were higher in Nizzana, whereas surface wettability was reduced in Lieberose. At both sites, BSCs caused extra WHC compared to the mineral substrate. Infiltration after wetting along both catenas generally reached a maximum after 10 min and decreased after 30 min. Carbohydrates were the dominating components in all of the BSCs studied, where the relative peak areas of carbohydrate-derived structures (60-110 ppm) amounted to 28-46\% and to 10-14\% of total C-peak areas, respectively. PCA revealed that the WHC of the substrate was closely related to the amount of silt and clay, whereas the BSC induced extra WHC was closely related to carbohydrates. It was further found that water repellency was positively related to carbohydrate C, but negatively related to alkyl C. Infiltration kinetics was attributed to polysaccharide hydration and swelling. Our findings support the hypothesis that hydraulic properties of BSCs are determined by extracellular polymeric substances (EPS) and soil texture. Hydraulic properties in BSCs result from the combination of chemical properties related to C compounds mainly dominated by carbohydrates and physical surface properties related to texture, porosity and water holding capacity.}, language = {en} } @misc{MykhailovaFischerIurchenko, author = {Mykhailova, Larysa and Fischer, Thomas and Iurchenko, Valentina}, title = {Distribution and fractional composition of petroleum hydrocarbons in roadside soils}, series = {Applied and Environmental Soil Science}, volume = {2013}, journal = {Applied and Environmental Soil Science}, number = {ID 938703}, doi = {10.1155/2013/938703}, pages = {1 -- 6}, language = {en} } @misc{WangFischerWieprechtetal., author = {Wang, Haijing and Fischer, Thomas and Wieprecht, Wolfgang and M{\"o}ller, Detlev}, title = {A predictive method for crude oil volatile organic compounds emission from soil: Evaporation and diffusion behavior investigation of binary gas mixtures}, series = {Environmental Science and Pollution Research}, journal = {Environmental Science and Pollution Research}, issn = {0944-1344}, doi = {10.1007/s11356-014-4049-3}, pages = {9}, abstract = {Due to their mobility and toxicity, crude oil volatile organic compounds (VOCs) are representative components for oil pipeline contaminated sites detection. Therefore, contaminated location risk assessment, with airborne light detection and ranging (LIDAR) survey, in particular, requires ground-based determinative methods for oil VOCs, the interaction between oil VOCs and soil, and information on how they diffuse from underground into atmosphere. First, we developed a method for determination of crude oil VOC binary mixtures (take n-pentane and n-hexane as examples), taking synergistic effects of VOC mixtures on polydimethylsiloxane (PDMS) solid-phase microextraction (SPME) fibers into consideration. Using this method, we further aim to extract VOCs from small volumes, for example, from soil pores, using a custom-made sampling device for nondestructive SPME fiber intrusion, and to study VOC transport through heterogeneous porous media. Second, specific surface Brunauer-Emmett-Teller (BET) analysis was conducted and used for estimation of VOC isotherm parameters in soil. Finally, two models were fitted for VOC emission prediction, and the results were compared to the experimental emission results. It was found that free diffusion mode worked well, and an empirical correction factor seems to be needed for the other model to adapt to our condition for single and binary systems.}, language = {en} } @misc{FischerSubbotina, author = {Fischer, Thomas and Subbotina, Maria}, title = {Climatic and soil texture threshold values for cryptogamic cover development: a meta analysis}, series = {Biologia}, volume = {69}, journal = {Biologia}, number = {11}, issn = {1336-9563}, doi = {10.2478/s11756-014-0464-7}, pages = {1520 -- 1530}, abstract = {In a global meta study, which contained 157 biological soil crust (BSC) samples from all climatic regions worldwide, climatic and soil texture threshold values favoring BSC development were derived. Response variable was the "relative crust biomass", which was computed per literature source as the ratio between each individual crust biomass value of the given study to the study maximum value reported. Four crust types were distinguished: cyanobacterial, lichen, green algal and moss crusts. To quantify threshold conditions at which crust biomass responded to differences in texture and climate, we (I) determined correlations between bioclimatic variables, (II) calculated generalized linear models to determine the effect of typical climatic variables with soil clay content and with study site as a random effect. (III) Thresholds of climatic and texture effects were identified using a regression tree. Three mean annual temperature classes for texture dependent BSC growth limitation were identified: (1) <9°C with a threshold value of 25\% silt and clay (limited growth on coarser soils), (2) 9-19°C, where texture did have no influence on relative crust biomass, and (3) >19°C at soils with <4 or >17\% silt and clay. Non of the precipitation related bioclimatic variables did influence the relative crust biomass significantly. Because biocrust development is limited under certain climatic and soil texture conditions, it is suggested to consider soil texture in biogeochemical modeling of cryptogamic ground covers.}, language = {en} } @inproceedings{FischerGypserSubbotinaetal., author = {Fischer, Thomas and Gypser, Stella and Subbotina, Maria and Veste, Maik}, title = {Hydraulic and nutritional feedback controls surface patchiness of biological soil crusts at a post-mining site}, series = {European Geosciences Union, General Assembly 2015, Vienna, Austria, 13 April - 17 May 2015}, booktitle = {European Geosciences Union, General Assembly 2015, Vienna, Austria, 13 April - 17 May 2015}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @inproceedings{MykhailovaFischerIurchenko, author = {Mykhailova, Larysa and Fischer, Thomas and Iurchenko, Valentina}, title = {Microbial activity and soil organic matter decay in roadside soils polluted with petroleum hydrocarbons}, series = {European Geosciences Union, General Assembly 2015, Vienna, Austria, 13 April - 17 May 2015}, booktitle = {European Geosciences Union, General Assembly 2015, Vienna, Austria, 13 April - 17 May 2015}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @misc{SubbotinaFischerMikhailovaetal., author = {Subbotina, Maria and Fischer, Thomas and Mikhailova, Lyudmila and Losev, Daniil}, title = {The influence of postagrogenic transformation on biological properties of soddy shallow clay loam podzolic soil in the Preduralie.}, series = {Agriculture \& Forestry}, volume = {62}, journal = {Agriculture \& Forestry}, number = {1}, issn = {1800-6492}, doi = {10.17707/AgricultForest.62.1.06}, pages = {59 -- 63}, language = {en} } @inproceedings{ZiemsFischerKrautzetal., author = {Ziems, Christian and Fischer, Ulrich and Krautz, Hans Joachim and Luschtinetz, Thomas and Lehmann, Jochen}, title = {Project presentation-Novel 3D porous electrode materials for more efficient alkaline water electrolysis-AEL3D}, series = {Nutzung regenerativer Energiequellen und Wasserstofftechnik 2016, 23. Symposium Nutzung Regenerativer Energiequellen und Wasserstofftechnik, Stralsund, 3. - 5. November 2016}, booktitle = {Nutzung regenerativer Energiequellen und Wasserstofftechnik 2016, 23. Symposium Nutzung Regenerativer Energiequellen und Wasserstofftechnik, Stralsund, 3. - 5. November 2016}, publisher = {Fachhochschule}, address = {Stralsund}, isbn = {978-3-9817740-1-6}, pages = {175 -- 181}, language = {en} } @misc{Fischer, author = {Fischer, Thomas}, title = {Humic supramolecular structures have polar surfaces and unpolar cores in native soil}, series = {Chemosphere}, volume = {183}, journal = {Chemosphere}, issn = {1879-1298}, doi = {10.1016/j.chemosphere.2017.05.125}, pages = {437 -- 443}, abstract = {It was the aim of our study to prove the hypothesis that humic substances (HS) in native soil are spatially arranged in descending order of polarity, meaning that highly polar supramolecular subunits shield less polar subunits against the free soil solution and form layers of descending polarity. To address this aim, we consecutively extracted humic substances from soil with 8 M (HS1), 4 M (HS2), 2 M (HS3), 1 M (HS4) and 0.5 M LiCl (HS5) solution in 0.2 M LiOH after Cu²⁺ adsorption in batch soil column experiments. Adsorption was performed for 1, 10 and 60 min with concentrations ranging from 9.5 to 110 mg L¹⁻Cu²⁺ in 0.02 M CaCl₂ solution. We assumed that high ionic strength facilitates extraction of most polar organic compounds, with polarity of the extracted HS decreasing with decreasing ionic strength, and that Cu extracted together with the successive HS solely formed coordination complexes, facilitating its use as a tracer for organic matter studies. We hypothesized a delayed Cu adsorption on the less polar fractions in case of spatial shielding due to interception on overlying fractions, and a concurrent Cu adsorption in case of random spatial arrangement. It was concluded that humic substances are shielded against each other in the order of descending polarity of the supramolecular subunits (free soil solution | HS1 | HS2 | HS3 | HS4 | HS5).}, language = {en} } @misc{KuhnTothGeppertetal., author = {Kuhn, Ramona and T{\´o}th, Elisabeth and Geppert, Helmut and Fischer, Thomas and Martienssen, Marion}, title = {Identification of the Complete Photodegradation Pathway of Ethylenediaminetetra(methylenephosphonic acid) in Aqueous Solution}, series = {Clean - soil, air, water : a journal of sustainability and environmental safety}, volume = {45}, journal = {Clean - soil, air, water : a journal of sustainability and environmental safety}, number = {5}, issn = {1863-0669}, doi = {10.1002/clen.201500774}, pages = {1 -- 8}, abstract = {This study aims at investigating the abiotic degradation pathway of ethylenediaminetetra(methylenephosphonic acid) (EDTMP) simulated applying UV irradiation. The degradation of EDTMP and formation of degradation products was determined using LC-MS and ³¹P-NMR. In the laboratory scale experiments, EDTMP was degraded within 30 min and the degradation products, iminodi(methylenephosphonic acid) (IDMP), ethylaminobis(methylenephosphonic acid) (EABMP), and amino- (methylenephosphonic acid) (AMPA), were simultaneously released. IDMP was the main degradation product of EDTMP. Therefore, we conclude that the initial cleavage of EDTMP is a heterolytically driven process, which starts the degradation process at the intramolecular C-N bond. In contrast, the main product of a possible homolytic C-C cleavage of methylaminobis(methylenephosphonic acid) could not be confirmed with either LC-MS or ³¹P-NMR. Additionally, there was no evidence for a primary attack on the C-P bond. All identified degradation products of EDTMP have been mineralized to carbon dioxide (CO₂). Three additional degradation products (M1, M2, and M3) have been found using the ³¹P-NMR analysis but have not yet been quantified using LC-MS. We assume that the unidentified degradation product M1 is related to m/z 312, M2 to m/z 341, and M3 to m/z 409. Thus we concluded that EDTMP undergoes photochemical conversion to IDMP, the main degradation product. EABMP and AMPA also accumulate, but in smaller amounts. All intermediates are further mineralized to CO₂.}, language = {en} } @inproceedings{RadowBreussHoeltgenetal., author = {Radow, Georg and Breuß, Michael and Hoeltgen, Laurent and Fischer, Thomas}, title = {Optimised Anisotropic Poisson Denoising}, series = {Image Analysis, 20th Scandinavian Conference, SCIA 2017, Troms{\o}, Norway, June 12-14, 2017, Proceedings, Part I}, booktitle = {Image Analysis, 20th Scandinavian Conference, SCIA 2017, Troms{\o}, Norway, June 12-14, 2017, Proceedings, Part I}, editor = {Sharma, Puneet and Filippo, Maria Bianchi}, publisher = {Springer}, address = {Cham}, isbn = {978-3-319-59126-1}, doi = {10.1007/978-3-319-59126-1_42}, pages = {502 -- 514}, language = {en} } @misc{MykhailovaFischerIurchenko, author = {Mykhailova, Larysa and Fischer, Thomas and Iurchenko, Valentina}, title = {Microbial activity and decomposition of soil organic matter in roadside soils contaminated with petroleum hydrocarbons}, series = {CLEAN - Soil Air Water}, journal = {CLEAN - Soil Air Water}, issn = {1863-0669}, doi = {10.1002/clen.201800132}, pages = {8}, abstract = {Petroleum hydrocarbons (PHs) are the most widespread organic pollutants of roadside soils, the reclamation of which is costly due to large areas affected, and natural PHs biodegradation is the only way of mitigating negative ecological consequences. This study aimed to investigate the microbial response to PHs in roadside soils and to identify soil organic matter (SOM) and PHs involved in biodegradation processes. To address this aim, soil respiration is related to light (chain-length ≤C14) medium (C15-C27), and heavy fractions (≥C28) of total PHs, and to SOM components: carbohydrates, proteins, lignin, aliphates, carbonyl/carboxyl, and char amounts of soils sampled at distances of up to 100 m from three roads in Kharkiv, Ukraine. A close relation between soil respiration and ratio of the light fraction to the sum of medium and heavy alkane fractions indicate the preferential mineralization of more biodegradable light PHs fractions. A positive relation between soil respiration and carbohydrate C, as well as negative correlation with aliphatic C, indicate preferred degradation of carbohydrates compared to more recalcitrant aliphates. Carbohydrate content increased and aliphatic C decreased with distance from the roads, and carbohydrates decreased with PHs concentration, indicating increased degradation of carbohydrates at high PHs concentrations (positive priming). It is concluded that microorganisms generate the energy required for PHs degradation by enhanced oxidation of native SOM where carbohydrates were of paramount importance.}, language = {en} } @misc{KuhnJenschBryantetal., author = {Kuhn, Ramona and Jensch, Robert and Bryant, Isaac Mbir and Fischer, Thomas and Liebsch, Stephan and Martienssen, Marion}, title = {The influence of selected bivalent metal ions on the photolysis of diethylenetriamine penta(methylenephosphonic acid)}, series = {Chemosphere}, journal = {Chemosphere}, number = {210}, issn = {0045-6535}, doi = {10.1016/j.chemosphere.2018.07.033}, pages = {726 -- 733}, abstract = {DTPMP is predominantly utilized as scale inhibitor. We investigated the reaction rates and degradation mechanism of DTPMP with and without addition of Fe²⁺, Mg²⁺ and Ca²⁺ by performing LC/MS and ³¹P-NMR analyses. DTPMP undergoes conversion with and without addition of bivalent metal ions. The initial cleavage of DTPMP is initiated at the C-N bond leading to release of IDMP as its major breakdown product. The release of smaller quantities of EABMP and AMPA confirmed the nucleophilic attack on the DTPMP amines. Oxidation of Fe²⁺ to Fe³⁺ during the initial 30 min indicated an intramolecular electron transfer changing the electron density distribution at the nitrogen centre, which increased the radical attack during UV irradiation. Independent of the fact that Fe acted as catalyst and Mg²⁺ and Ca²⁺ acted as reactants, we found no significant differences in their degradation mechanisms. However, the reaction rates were strongly affected by the addition of the bivalent metal ions as Fe²⁺ accelerated most DTPMP degradation followed by Mg²⁺ and Ca²⁺. The UV treatment without metal ion addition was four times slower compared with Fe²⁺ addition. We conclude that in environments rich in ferrous iron and/or at reduced redox potential, photolysis of DTPMP will be catalysed by iron and will lead to accumulation of IDMP, EABMP and AMPA and several other none-quantifiable breakdown products.}, language = {en} } @misc{KuhnJenschBryantetal., author = {Kuhn, Ramona and Jensch, Robert and Bryant, Isaac Mbir and Fischer, Thomas and Liebsch, Stephan and Martienssen, Marion}, title = {Rapid sample clean-up procedure for aminophosphonate determination by LC/MS analysis}, series = {Talanta}, volume = {208}, journal = {Talanta}, issn = {0039-9140}, doi = {10.1016/j.talanta.2019.120454}, pages = {6}, abstract = {Aminophosphonates are commonly utilised for complexing bivalent ions such as calcium and magnesium. With regard to environmental samples, the analysis of these highly polar compounds is still challenging due to matrix effects and lacking analytical standard methods. We have recently developed a LC/MS method for common aminophosphonates without derivatisation. This LC/MS method delivers precise and accurate measurement for standard samples with very low concentration of cations disturbing the analysis. However, due to matrix effects this LC/MS method requires a sample clean-up being also applicable to natural water or wastewater samples. We developed and optimised a sample clean-up procedure applying strong cation exchange resin Dowex 50WX8. This clean-up allows a single LC/MS analysis of hydroxyethelidene(diphosphonic acid) (HEDP), aminotris(methylenephosphonic acid) (ATMP), ethylenediaminetetra(methyloenephosphonic acid) (EDTMP), diethylenetriaminepenta(methylenephosphonic acid) (DTPMP) and its major intermediates amino(methylphosphonic acid) (AMPA) and iminodi(methylenephosphonic acid) (IDMP). We compared different test conditions with six aminophosphonates in either ultra pure water or tap water. The latter was used to simulate cation concentrations typical for natural waters. To elute all aminophosphonate including AMPA, ammonium acetate addition was necessary. The addition of ammonium acetate was combinable with all tested aminophosphonates and provides high sample quality for LC/MS analysis. For acceptable recovery, the smallest aminophosphonate AMPA required the highest addition of ammonium acetate (1000 mg L-1) during the sample clean-up. Finally, the optimised clean-up procedure was successfully applied to identify and quantify phosphonates from an industrial wastewater sample. The sample clean-up procedure is simple, cheap, rapid and precise and can be further combined with solid phase extraction and more sensitive LC/MS methods.}, language = {en} } @misc{WannerBirkhoferFischeretal., author = {Wanner, Manfred and Birkhofer, Klaus and Fischer, Thomas and Shimizu, Miki and Shimano, Satoshi D. and Puppe, Daniel}, title = {Soil Testate Amoebae and Diatoms as Bioindicators of an Old Heavy Metal Contaminated Floodplain in Japan}, series = {Microbial Ecology}, volume = {79}, journal = {Microbial Ecology}, number = {1}, issn = {1432-184X}, doi = {10.1007/s00248-019- 01383-x}, pages = {123 -- 133}, language = {en} } @misc{KuhnJenschBryantetal., author = {Kuhn, Ramona and Jensch, Robert and Bryant, Isaac Mbir and Fischer, Thomas and Liebsch, Stephan and Martienssen, Marion}, title = {Photodegradation of ethylenediaminetetra(methylenephosphonic acid) - The effect of the system configuration}, series = {Journal of Photochemistry \& Photobiology A: Chemistry}, volume = {388}, journal = {Journal of Photochemistry \& Photobiology A: Chemistry}, issn = {1010-6030}, doi = {10.1016/j.jphotochem.2019.112192}, pages = {9}, abstract = {Photodegradation of aminophosphonates such as ethylenediaminetetra(methylenephosphonic acid) (EDTMP) is recently assumed being the major degradation pathway in aquatic environments. Several photolysis studies were reported about EDTMP and possible breakdown products occurring in natural ecosystems. Reliable prediction of environmental photolysis of parent compounds and possible release of breakdown products requires different set-up conditions and varying the parameters influencing the photodegradation. We studied the influence of three different system configurations during UV degradation of EDTMP. These three configurations differed either in geometry and/or treated sample volumes. System 1 was equipped with a direct cooling jacket at the UV lamp. System 2 had the geometry of system 1 but there was no usage of a direct cooling jacket. System 3 was a gas-tight system with a larger sample volume. Using the chemical actinometer potassium ferrioxalate, we determined the highest photon flux for system 3 followed by system 2 and 1. In addition, we performed scavenger experiments with methanol and ascorbic acid in order to prove the dominating radical species. In system 1, the addition of methanol showed almost no effect while the ascorbic acid resulted in a reduction of 57.1\% orthophosphate released. Therefore we conclude that in system 1 the radical-drive degradation of EDTMP is mainly based on superoxide radicals. In system 2 and 3 both radical species, i.e., hydroxyl radicals and superoxide radicals, contribute to the photodegradation of EDTMP. We determined different half-lives for EDTMP for the three different systems configurations. For system 1, the estimated half-life achieved was 14.09 ± 0.15 min. For system 2 and 3, the half-lives were almost similar and averaged 4.75 ± 0.05 min and 5.02 ± 0.20 min, respectively. Contrary to our assumption to also find the highest degradation rate for system 3, we found the highest degradation rate for system configuration 2 as a result of the differences in the construction and geometry of the three systems. Our findings lead us to recommend the three system configuration for different research purposes. Thus, we recommend system 1 for detailed studies on the degradation pathway of the parent compound and their breakdown products. System 2 is recommended as a suitable configuration for kinetic studies of the parent compound. And finally, we recommend the system configuration 3 for complete mass balances. The gas-tight system allows determining all soluble and gaseous compounds.}, language = {en} } @misc{KidronFischerXiao, author = {Kidron, Giora J. and Fischer, Thomas and Xiao, Bo}, title = {The ambivalent effect of biocrusts on evaporation: Can the contradictory conclusions be explained? A review}, series = {Geoderma}, volume = {Vol. 416}, journal = {Geoderma}, issn = {1872-6259}, doi = {10.1016/j.geoderma.2022.115805}, pages = {13}, language = {en} } @misc{FischerMarchettiDeschmannAssisetal., author = {Fischer, Thomas and Marchetti-Deschmann, Martina and Assis, Ana Cristina and Elad, Michal Levin and Algarra, Manuel and Barac, Marko and Bogdanovic Radovic, Iva and Cicconi, Flavio and Claes, Britt and Frascione, Nunzianda and George, Sony and Guedes, Alexandra and Heaton, Cameron and Heeren, Ron and Lasic, Violeta and Lerma, Jos{\´e} Luis and del Valle Martinez de Yuso Garcia, Maria and Nosko, Martin and O'Hara, John and Oshina, Ilze and Palucci, Antonio and Pawlaczyk, Aleksandra and Posp{\´i}škov{\´a}, Krist{\´y}na and de Puit, Marcel and Radodic, Ksenija and Rēpele, Māra and Ristova, Mimoza and Romolo, Francesco Saverio and Šafař{\´i}k, Ivo and Siketic, Zdravko and Spigulis, Janis and Szynkowska-Jozwik, Malgorzata Iwona and Tsiatsiuyeu, Andrei and Vella, Joanna and Dawson, Lorna and R{\"o}diger, Stefan and Francese, Simona}, title = {Profiling and imaging of forensic evidence - A pan-European forensic round robin study part 1: Document forgery}, series = {Science \& Justice}, volume = {62}, journal = {Science \& Justice}, number = {4}, issn = {1876-4452}, doi = {10.1016/j.scijus.2022.06.001}, pages = {433 -- 447}, language = {en} } @misc{KidronLichnerFischeretal., author = {Kidron, Giora J. and Lichner, Lubomir and Fischer, Thomas and Starinsky, Abraham and Or, Dani}, title = {Mechanisms for biocrust-modulated runoff generation - A review}, series = {Earth-Science Reviews}, volume = {231}, journal = {Earth-Science Reviews}, issn = {0012-8252}, doi = {10.1016/j.earscirev.2022.104100}, pages = {1 -- 22}, language = {en} } @misc{KrisponeitFischerEsseretal., author = {Krisponeit, Jon-Olaf and Fischer, Simon and Esser, Sven and Moshnyaga, Vasily and Schmidt, Thomas and Piper, Louis F. J. and Flege, Jan Ingo and Falta, Jens}, title = {The morphology of VO2/TiO2(001): terraces, facets, and cracks}, series = {Scientific Reports}, volume = {10}, journal = {Scientific Reports}, issn = {2045-2322}, doi = {10.1038/s41598-020-78584-9}, pages = {8}, abstract = {Vanadium dioxide (VO2) features a pronounced, thermally-driven metal-to-insulator transition at 340 K. Employing epitaxial stress on rutile TiO2(001) substrates, the transition can be tuned to occur close to room temperature. Striving for applications in oxide-electronic devices, the lateral homogeneity of such samples must be considered as an important prerequisite for efforts towards miniaturization. Moreover, the preparation of smooth surfaces is crucial for vertically stacked devices and, hence, the design of functional interfaces. Here, the surface morphology of VO2/TiO2(001) films was analyzed by low-energy electron microscopy and diffraction as well as scanning probe microscopy. The formation of large terraces could be achieved under temperature-induced annealing, but also the occurrence of facets was observed and characterized. Further, we report on quasi-periodic arrangements of crack defects which evolve due to thermal stress under cooling. While these might impair some applicational endeavours, they may also present crystallographically well-oriented nano-templates of bulk-like properties for advanced approaches.}, language = {en} } @misc{SchmidtAhrensFlegeetal., author = {Schmidt, Thomas and Ahrens, Christian and Flege, Jan Ingo and Jaye, Cherno and Fischer, Daniel A. and Falta, Jens}, title = {Growth of Epitaxial 3,4,9,10-Perylene Tetracarboxylic Dianhydride on Bi-Terminated Silicon}, series = {Journal of Physical Chemistry C}, volume = {123}, journal = {Journal of Physical Chemistry C}, number = {12}, issn = {1932-7447}, doi = {10.1021/acs.jpcc.8b10396}, pages = {7097 -- 7109}, abstract = {The epitaxial quality of thin films crucially depends on their interaction with the substrate. Up to now, Ag-terminated Si(111) has been employed as the model substrate for the growth of 3,4,9,10-perylene tetracarboxylic dianhydride (PTCDA) on semiconductors. In this study, we will show that Bi termination results in PTCDA films of superior epitaxial quality. We have studied the growth of PTCDA on bismuth-passivated Si(111) in detail by means of spot profile analysis of low-energy electron diffraction (SPA-LEED), X-ray photoemission spectroscopy (XPS), near-edge X-ray absorptionfine structure (NEXAFS), and scanning tunneling microscopy (STM). The XPS results reveal the presence of intact PTCDA molecules on the surface upon adsorption. NEXAFS data indicate the PTCDA molecules being oriented with their molecular plane parallel to the surface. STM shows a very smooth growth front of the PTCDA film, preserving the step structure of the substrate. High-resolution SPA-LEED data demonstrate the presence of a multidomain surface with a rich variety of PTCDA surface structures, which were identified to be most prominently herring-bone polytypes. However, in the monolayer range, quadratic brick-wall structures and a nearly square-like structure as well as a perylene-like structure have also been found. Despite the simultaneous presence of multiple domains, the individual domains show excellent lateral ordering, with larger domain sizes as compared to the case of Ag-terminated Si(111).}, language = {en} } @misc{WangGeppertFischeretal., author = {Wang, Haijing and Geppert, Helmut and Fischer, Thomas and Wieprecht, Wolfgang and M{\"o}ller, Detlef}, title = {Determination of Sucrose in Honey with Derivatization/Solid-Phase-Microextraction and Gas-Chromatography/Mass Spectrometry.}, series = {Journal of Chromatographic Science}, volume = {53}, journal = {Journal of Chromatographic Science}, number = {9}, doi = {10.1093/chromsci/bmv044}, pages = {1427 -- 1431}, abstract = {A new method for the determination of sucrose in honey with derivatization solid-phase microextraction and gas chromatography/mass spectrometry (D-SPME-GC/MS) was developed. The method incorporates a sample derivatization with acetic anhydride using N-methylimidazole as the catalyst and the subsequent enrichment of the analyte in a Polyacrylate-SPME fiber. Results show that 100 µL N-methylimidazole and 800 µL acetic anhydride were sufficient to complete the acetylation for sucrose in 100 µL aqueous sample at room temperature. For SPME, an enrichment time of 30 min was sufficient. SPME was performed by immersing the fiber into the solution with additional vibration. Then, the analyte was desorbed for 5 min at 280°C in the GC/MS injection port with splitless mode. The present method exhibits good linearity at a concentration range of 0.3-8\% of sucrose in honey with excellent regression (R = 0.9993). The method has been successfully applied to the control of sucrose adulteration in honey.}, language = {en} } @misc{WangFischerWieprechtetal., author = {Wang, Haijing and Fischer, Thomas and Wieprecht, Wolfgang and M{\"o}ller, Detlev}, title = {A predictive method for volatile organic compounds emission from soil: Evaporation and diffusion behavior investigation of a representative component of crude oil}, series = {Science of the Total Environment}, volume = {530-531}, journal = {Science of the Total Environment}, issn = {1879-1026}, doi = {10.1016/j.scitotenv.2015.05.063}, pages = {38 -- 44}, language = {en} } @misc{WangGeppertFischeretal., author = {Wang, Haijing and Geppert, Helmut and Fischer, Thomas and Wieprecht, Wolfgang and M{\"o}ller, Detlev}, title = {Determination of volatile organic and polycyclic aromatic hydrocarbons in crude oil with efficient gas-chromatographic methods}, series = {Journal of Chromatographic Science}, volume = {53}, journal = {Journal of Chromatographic Science}, number = {5}, issn = {1945-239X}, doi = {10.1093/chromsci/bmu113}, pages = {647 -- 654}, abstract = {Determination of volatile organic compounds (VOCs) in crude oil, such as super volatile organic compounds (super VOCs) and simple polycyclic aromatic hydrocarbons (PAHs), is vital for targeting crude oil spill spots. In this study, a static headspace gas chromatography flame ionization detection method was established for determination of super VOCs in crude oil with both external and internal standard determination, which can be used in the field when using portable gas chromatography. Identification was done by comparing the retention time with the corresponding standards and quantitation was done with a new one-drop method. Another simplified and efficient method was performed to analyze volatile PAHs in crude oil, which can also be used in field analysis. Toluene was used as the extraction solvent for PAHs in crude oil. Method validation for both analyses was satisfactory. The result showed that n-butane and n-pentane were maximum super VOCs and naphthalene, phenanthrene and fluorene were the main PAHs in the crude oil studied. The super VOCs quantity ranged from 3 to 6\% and the main PAHs consisted of 0.02-0.06\% of studied crude oil.}, language = {en} } @inproceedings{FischerSubbotina, author = {Fischer, Thomas and Subbotina, Maria}, title = {Soil texture and climatc conditions for biocrust growth limitation: a meta analysis}, series = {European Geosciences Union, General Assembly 2015, Vienna, Austria, 13 April - 17 May 2015}, booktitle = {European Geosciences Union, General Assembly 2015, Vienna, Austria, 13 April - 17 May 2015}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @inproceedings{FischerYairGeppertetal., author = {Fischer, Thomas and Yair, Aaron and Geppert, Helmut and Veste, Maik}, title = {Water repellency and infiltration of biological soil crusts on an arid and a temperate dunes}, series = {European Geosciences Union, General Assembly 2014, Vienna, Austria, 27 April - 02 May 2014}, booktitle = {European Geosciences Union, General Assembly 2014, Vienna, Austria, 27 April - 02 May 2014}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @inproceedings{Fischer, author = {Fischer, Thomas}, title = {Initial pedogenesis in biological soil crusts}, series = {Nasledie I. V. Tjurina v sovremennych issledovanijach v počvovedenii: materialy Meždunarodnoj naučnoj konferencii, Kazan', 15 - 17, oktjabrja 2013}, booktitle = {Nasledie I. V. Tjurina v sovremennych issledovanijach v počvovedenii: materialy Meždunarodnoj naučnoj konferencii, Kazan', 15 - 17, oktjabrja 2013}, publisher = {Izdat. Otečestvo}, address = {Kazan', Russian Federation}, isbn = {978-5-9222-0726-3}, pages = {19 -- 21}, language = {en} } @misc{BusseFischerGebaueretal., author = {Busse, Ralph-Peter and Fischer, Gert and Gebauer, Gert and H{\"o}fler, Frank and Junker, Sabine and Kramer, Thomas and Opperskalski, Stephan and Potthoff, Ulrich and Remus, Ricardo and Schlamkow, Christian and Schmidt, Wolfgang and Scobel, Ekkehard and Stopp, Horst and Strangfeld, Peter and Trang, Ngyen Thi Thu and V{\"o}lker, Eduard and Vukorep, Ilija and Weidhase, Frieder and Winzer, Reinhard}, title = {Floating Architecture - Construction on and near water}, editor = {Stopp, Horst and Strangfeld, Peter}, publisher = {LIT-Verlag}, address = {Berlin}, isbn = {978-3-643-90910-7}, pages = {134}, abstract = {The publishers are receiving more and more inquiries about the topic "Floating Architecture", particularly about technical details, water chemistry, as well as ice and wave problems. Since there is a lack of technical literature on this topic, most students working on projects or theses related to this topic send their inquiries. A time of general and quick changes results in a large number of daily publications. Therefore it is difficult to understand why there is a lack of lit-erature about floating structures. One has to consider that sea levels will continue to rise and consequently a larger number of people will have to live on the surface of the sea. Obviously, some expert knowledge is required which needs a longer period of time to be gained through scientific advancements and experience. The publishers, who have been dealing with the topic of floating houses for some years, are grateful to the authors for their agreement to allow the publication of their papers on floating architecture. These papers were mainly prepared for two conferences on floating architecture held in the study centre of the IBA building, Großr{\"a}schen. Therefore, the reader should know that, along with the usual papers, only a selection of self-explaining transparencies is shown in order to meet the printing requirements. The included list of both the authors and their addresses makes it easy for interested people to send any inquiries to them. A short introduction as well as an outlook at the end of each paper is meant to draw attention to current events in order to be able to promptly identify opportunities and risks connected with living on the water.}, language = {en} } @misc{HinzHafarFischer, author = {Hinz, Christoph and Hafar, Brian and Fischer, Thomas}, title = {Heavy metal mobilisation of salt affected soils and sediments: Assessing the role of chloride complex formation.}, series = {European Geosciences Union, General Assembly 2019, Vienna, Austria, 7-12 April 2019}, journal = {European Geosciences Union, General Assembly 2019, Vienna, Austria, 7-12 April 2019}, address = {Katlenburg-Lindau}, abstract = {Terrestrial and aquatic ecosystems are increasingly exposed to high level of salt (NaCl) concentrations. Impacts of increased salt concentration on mobilisation of heavy metals have been shown for road side soils receiving de-icing salt, for sediments and soils exposed to salt water intrusions, and soils and aquifers receiving runoff from salt mines. In fact, this study was motivated by the impact of salt dumps on soil and groundwater observed for potash mines in the central part of Germany. The objectives of this contribution is to asses the impact of NaCl concentration on heavy metal mobilization using speciation modelling. In particular, we focus on the effect of chloride complex formation in solution and how strongly this complex formation is "extracting" heavy metal cation from soil and sediments substrates. As experimental data for speciation at very high ionic strength is not readily available and not easily measurable, we focus on PHREEQC modelling to assess NaCl concentration ranges up to 3 M, needing to employ Pitzer equation as the activity model. In order to determine the competition of surface reaction and complex formation in aqueous solution, we used three reaction models: i) surface complexation with a high and low affinity site for iron hydroxide, ii) a heterogeneous binding site model for humic acids and iii) ion exchange as described with Rothmund-Kornfeld equation We did a series of simulations for Zn, Cd and Pb. Species distribution for the aqueous phase and the solid surfaces where determined by increasing NaCl solutions for a given total heavy metal concentration. In nearly all simulations conducted, the difference between simulations allowing chloride complexes to form and simulations where complexation is disabled, showed the emergence of a characteristic concentration range of NaCl for which the effect of chloride complexation reaches a maximum. In general, the range of highest sensitivity concerning mobilization occurs within the range of 1-3M NaCl for all simulations. At the lower end of this range shows the highest sensitivity to NaCl changes and is determined by several factors including the affinity to bonding sites and the speciation of an element along the salinity gradient. The peak of this curve is controlled by the point along the salinity gradient where the majority of heavy metal has been mobilized from the surface phase. One important outcome of this study is, that increasing NaCl background concentration behaves in a nonlinear way that is determined by the heterogeneity of the surface binding sites and that there is no simple way of assessing the mobilization potential of chloride complexation in soils and sediments.}, language = {en} } @misc{KuhnJenschFischeretal., author = {Kuhn, Ramona and Jensch, Robert and Fischer, Thomas and Keuler, Klaus and Bryant, Isaac Mbir and Martienssen, Marion}, title = {Sunlight Degradation of the Aminophosphonate Diethylenetriamine Penta-(Methylenephosphonic Acid)}, series = {Solar}, volume = {2}, journal = {Solar}, number = {2}, issn = {2673-9941}, doi = {10.3390/solar2020009}, pages = {141 -- 157}, abstract = {Aminophosphonate diethylenetriamine penta(methylenephosphonic acid) (DTPMP) is a scale inhibitor commonly used in several industries. DTPMP is suspected to cause anthropogenic pollution through discharge into the aquatic environment. DTPMP is assumed to be degraded by sunlight radiation. We recently predicted a preliminary degradation pathway of DTPMP applyingUV treatment. Currently, we have not yet evidenced that DTPMP shows the same degradation pattern with natural sunlight. One major reason leads to the fact that the light spectrum emitted by UV lamps does not completely represent the natural sunlight spectrum, and the emitted UVB and UVA irradiation flux is much higher than for solar light. For that reason, the degradation pattern and kinetics might be different between artificial UV treatment and natural sunlight treatment. Here, we investigated whether DTPMP is degradable under natural sunlight radiation, and whether the degradation mechanisms determined through UV treatment are transferable to sunlight. We investigated five different treatment conditions, i.e., DTPMP degradation in direct or diffuse sunlight, in diffuse sunlight with addition of Ca2+ or Mg2+, and in diffuse sunlight with local TW. Our experiment was carried out from March 2021 to October 2021. We performed LC/MS analyses and measured the release of o-PO4 3 . DTPMP was degraded with all five treatment conditions. The fastest DTPMP degradation occurred in direct and diffuse sunlight without addition of bivalent cations. The addition of Ca2+ and Mg2+ resulted in inhibited degradation. Similar effects occurred for sunlight treatment with local TW. We evidenced different degradation mechanisms for DTPMP depending on the presence of alkaline earth metals as we previously proposed for UV-treated DTPMP. However, both degradation mechanisms of DTPMP belong to the same degradation pathway determined with UV treatment. Therefore, we conclude that DTPMP undergoes a similar degradation pathway in sunlight as compared to UV light.}, language = {en} } @inproceedings{FischerVesteMykhailova, author = {Fischer, Thomas and Veste, Maik and Mykhailova, Larysa}, title = {Ecological Maturity and Drought Stress of Biological Soil Crusts along a Central European Inland Dune Catena}, series = {European Geosciences Union, General Assembly 2014, Vienna, Austria, 27 April - 02 May 2014}, booktitle = {European Geosciences Union, General Assembly 2014, Vienna, Austria, 27 April - 02 May 2014}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @inproceedings{FischerVesteWieheetal., author = {Fischer, Thomas and Veste, Maik and Wiehe, Wolfgang and Lange, Philipp}, title = {Linking microstructural and spectroscopic analysis of biological soil crusts - investigation of organo-mineral interactions}, series = {6th International Symposium on Ecosystem Behaviour BIOGEOMON 2009}, booktitle = {6th International Symposium on Ecosystem Behaviour BIOGEOMON 2009}, editor = {Ukonmaanaho, Liisa and Nieminen, Tiina Maileena and Starr, Michael}, publisher = {Finnish Forest Research Institut}, address = {Vantaa, Finland}, isbn = {978-951-40-2177-0}, pages = {S. 412}, language = {en} } @misc{EissaFischerMausolfetal., author = {Eissa, Mohamed Hussein and Fischer, Gunter and Mausolf, Thomas and R{\"u}cker, Holger and Malignaggi, Andrea and Kahmen, Gerhard}, title = {220-320-GHz J-Band 4-Way Power Amplifier in Advanced 130-nm BiCMOS Technology}, series = {IEEE Microwave and Wireless Components Letters}, volume = {32}, journal = {IEEE Microwave and Wireless Components Letters}, number = {11}, issn = {1531-1309}, doi = {10.1109/LMWC.2022.3181407}, pages = {1335 -- 1338}, language = {en} } @misc{ZhangGeyerSilvaetal., author = {Zhang, Tingyi and Geyer, Thomas and Silva, Charitha de and Fischer, Jeoffrey and Doolan, Con and Moreau, Danielle J.}, title = {Experimental Investigation of Tip Vortex Formation Noise Produced by Wall-Mounted Finite Airfoils}, series = {Journal of Aerospace Engineering}, volume = {34}, journal = {Journal of Aerospace Engineering}, number = {6}, issn = {1943-5525}, doi = {10.1061/(ASCE)AS.1943-5525.0001315}, language = {en} } @inproceedings{IurchenkoMykhailovaFischer, author = {Iurchenko, Valentina and Mykhailova, Larysa and Fischer, Thomas}, title = {Kinetic Characteristics of Petrochemicals Transposition and Accumulation in Soils of Roadside Area}, series = {Transbaltica 2013 Conference Proceedings, 09.-10. May 2013, Vilnius, Lithuania}, booktitle = {Transbaltica 2013 Conference Proceedings, 09.-10. May 2013, Vilnius, Lithuania}, doi = {10.3846/transbaltica2013.016}, pages = {4}, language = {en} } @misc{FranzenFischer, author = {Franzen, Christoph and Fischer, Thomas}, title = {Removal of Iron Crusts from Sandstone Sculptures in a Fountain}, series = {Environmental Earth Sciences}, volume = {81}, journal = {Environmental Earth Sciences}, number = {7}, issn = {1866-6299}, doi = {10.1007/s12665-022-10302-2}, language = {en} } @misc{ManzoniChakrawalFischeretal., author = {Manzoni, Stefano and Chakrawal, Arjun and Fischer, Thomas and Schimel, Joshua P. and Porporato, Amilcare and Vico, Giulia}, title = {Rainfall intensification increases the contribution of rewetting pulses to soil respiration}, series = {Biogeosciences}, volume = {17}, journal = {Biogeosciences}, number = {15}, doi = {10.5194/bg-17-4007-2020}, pages = {4007 -- 4023}, abstract = {Soil drying and wetting cycles promote carbon (C) release through large heterotrophic respiration pulses at rewetting, known as the "Birch" effect. Empirical evidence shows that drier conditions before rewetting and larger changes in soil moisture at rewetting cause larger respiration pulses. Because soil moisture varies in response to rainfall, these respiration pulses also depend on the random timing and intensity of precipitation. In addition to rewetting pulses, heterotrophic respiration continues during soil drying, eventually ceasing when soils are too dry to sustain microbial activity. The importance of respiration pulses in contributing to the overall soil heterotrophic respiration flux has been demonstrated empirically, but no theoretical investigation has so far evaluated how the relative contribution of these pulses may change along climatic gradients or as precipitation regimes shift in a given location. To fill this gap, we start by assuming that heterotrophic respiration rates during soil drying and pulses at rewetting can be treated as random variables dependent on soil moisture fluctuations, and we develop a stochastic model for soil heterotrophic respiration rates that analytically links the statistical properties of respiration to those of precipitation. Model results show that both the mean rewetting pulse respiration and the mean respiration during drying increase with increasing mean precipitation. However, the contribution of respiration pulses to the total heterotrophic respiration increases with decreasing precipitation frequency and to a lesser degree with decreasing precipitation depth, leading to an overall higher contribution of respiration pulses under future more intermittent and intense precipitation. Specifically, higher rainfall intermittency at constant total rainfall can increase the contribution of respiration pulses up to ∼10 \% or 20 \% of the total heterotrophic respiration in mineral and organic soils, respectively. Moreover, the variability of both components of soil heterotrophic respiration is also predicted to increase under these conditions. Therefore, with future more intermittent precipitation, respiration pulses and the associated nutrient release will intensify and become more variable, contributing more to soil biogeochemical cycling.}, language = {en} } @misc{ZhangMoreauGeyeretal., author = {Zhang, Tingyi and Moreau, Danielle J. and Geyer, Thomas and Fischer, Jeoffrey and Doolan, Con}, title = {Dataset on tip vortex formation noise produced by wall-mounted finite airfoils with sinusoidal and porous tip geometries}, series = {Data in Brief}, volume = {30}, journal = {Data in Brief}, issn = {2352-3409}, doi = {10.1016/j.dib.2020.105471}, pages = {10}, language = {en} } @misc{ZhangMoreauGeyeretal., author = {Zhang, Tingyi and Moreau, Danielle J. and Geyer, Thomas and Fischer, Jeoffrey and Doolan, Con}, title = {Dataset on tip vortex formation noise produced by wall-mounted finite airfoils with flat and rounded tip geometries}, series = {Data in Brief}, volume = {28}, journal = {Data in Brief}, issn = {2352-3409}, doi = {10.1016/j.dib.2019.105058}, pages = {8}, language = {en} } @misc{Fischer, author = {Fischer, Thomas}, title = {PCA-based Supervised Identification of Biological Soil Crusts in Multispectral Images}, series = {MethodsX}, volume = {6}, journal = {MethodsX}, issn = {2215-0161}, doi = {10.1016/j.mex.2019.03.013}, pages = {764 -- 772}, abstract = {It was the aim of the method development to classify types of various biological soil crusts (biocrusts) using principle component analysis (PCA) on multispectral images. To address this aim, visible (RGB) and NIR images of bare sandy soil, algal and moss biocrusts were registered, per channel reflection values were determined using a calibration color chart on a pixel basis, and a PCA was performed on the unfolded RGB-NIR reflectance hypercubes (i.e. three-dimensional hypercubes were transformed into x.y × λ 2D-matrices with λ channels serving as variables for PCA). The classification approach was based on the hypothesis that biocrust types map specifically in PCA ordination plots, meaning that distinct regions in ordination plots may be assigned specifically to individual biocrust types. Reallocation of the pixels assigned to biocrust types to their respective image coordinates would then yield biocrust classification plots. Allows manual selection of features or identification of given features in PCA ordination plots. Fully permits the selection of relevant and omission of irrelevant, as well as identification of unknown classes. It is not restricted to RGB-NIR multispectral data only, but may be applied to any type of multimodal imaging data.}, language = {en} } @misc{FischerYairVeste, author = {Fischer, Thomas and Yair, Aaron and Veste, Maik}, title = {Microstructure and hydraulic properties of biological soil crusts on sand dunes: a comparison between arid and temperate climates}, series = {Biogeosciences Discuss}, volume = {9}, journal = {Biogeosciences Discuss}, doi = {10.5194/bgd-9-12711-2012}, pages = {12711 -- 12734}, abstract = {We studied the relationships between crust microstructure, infiltration and water holding capacity under arid and temperate conditions (Factor A: Climate) on biological soil crusts (BSCs) sampled along a catena on mobile sand dunes (Factor B: Catena). The arid study site was located near Nizzana, Israel (precipitation: 86mm a-1, PET: ca. 2500mm a-1) and the temperate site near Lieberose, Germany (precipitation: 569mm a-1, PET: ca. 780mm a-1). BSCs were sampled near the dune crest, at the centre of the dune slope and at the dune base at each site. Scanning electron microscopy (SEM) was used to characterize BSC morphology and microstructure. Infiltration was determined using microinfiltrometry under controlled moisture conditions in the lab. Water holding capacities were determined after water saturation of the dry BSCs. Wettability of the crusts was characterized using a "repellency index", which was calculated from water and ethanol sorptivities. Irrespective of the climate, an accumulation of fine particles in the BSCs was found, increasing along the catena from dune crest to dune base. Texture was finer and water holding capacities of the underlying substrate were higher at the arid site, whereas surface wettability was reduced at the temperate site. At both sites, BSCs caused extra water holding capacity compared to the substrate. Infiltration rates decreased along the catena and were generally lower at the dune slope and base of the arid site. A mechanism of crust stabilization is proposed where BSCs benefit from increased texture and biomass mediated water supply, and where the water supply to higher plants was limited due to alteration of physico-chemical surface properties under temperate conditions.}, language = {en} } @misc{FischerVesteWieheetal., author = {Fischer, Thomas and Veste, Maik and Wiehe, Wolfgang and Lange, Philipp}, title = {How biological crusts are stabilizing the soil surface? The development of organo-mineral interactions in the initial phase}, series = {EGU General Assembly 2009, Vienna, Austria, 19 - 24 April 2009}, journal = {EGU General Assembly 2009, Vienna, Austria, 19 - 24 April 2009}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @misc{MykhailovaFischerIurchenko, author = {Mykhailova, Larysa and Fischer, Thomas and Iurchenko, Valentina}, title = {Deposition of petroleum hydrocarbons with sediment trapped in snow in roadside areas}, series = {Journal of Environmental Engineering and Landscape Management}, volume = {22}, journal = {Journal of Environmental Engineering and Landscape Management}, number = {3}, issn = {1822-4199}, doi = {10.3846/16486897.2014.889698}, pages = {237 -- 244}, abstract = {Total petroleum hydrocarbon (TPH) deposition rates were determined along various roads using the natural snow cover as deposition trap. Daily deposition rates decreased with distance from the roads, which coincided with long-term TPH accumulation in roadside soils. Scanning electron microscopy (SEM-EDX) of the snow meltwater sediment revealed occurrence of carbon-rich plaques, which were identified as hydrocarbons using FTIR-microscopy. GC-MS revealed that the compounds extracted from the sediment consisted of an unresolved complex hydrocarbon mixture (UCM). Individual n-alkanes could not be resolved in the sediment extract, whereas TPHs extracted from soils contained a series of n-alkanes peaking at C25-C27. The proportion of UCM compounds from TPHs decreased with distance from road. We conclude that high-boiling hydrocarbons bind to coarse mineral dust and/or to splash water and vehicle spray, which preferentially deposit within a 10 m roadside strip.}, language = {en} } @misc{SchlykowManganelliRoemeretal., author = {Schlykow, Viktoria and Manganelli, Constanza Lucia and R{\"o}mer, Friedhard and Clausen, Caterina J. and Augel, Lion and Schulze, J{\"o}rg and Katzer, Jens and Schubert, Michael Andreas and Witzigmann, Bernd and Schroeder, Thomas and Capellini, Giovanni and Fischer, Inga Anita}, title = {Ge(Sn) nano-island/Si heterostructure photodetectors with plasmonic antennas}, series = {Nanotechnology}, volume = {31}, journal = {Nanotechnology}, number = {34}, issn = {1361-6528}, doi = {10.1088/1361-6528/ab91ef}, pages = {11}, language = {en} } @inproceedings{FischerVesteEiseleetal., author = {Fischer, Thomas and Veste, Maik and Eisele, Andreas and Bens, Oliver and Spyra, Wolfgang and H{\"u}ttl, Reinhard F.}, title = {High resolution mapping of Normalized Difference Vegetation Indices (NDVI) of biological soil crusts}, series = {EGU General Assembly 2012, held 22-27 April, 2012 in Vienna}, booktitle = {EGU General Assembly 2012, held 22-27 April, 2012 in Vienna}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @inproceedings{KruemmelbeinFischerRaabetal., author = {Kr{\"u}mmelbein, Julia and Fischer, Scarlett and Raab, Thomas and H{\"u}ttl, Reinhard F.}, title = {Bodenphysikalische Kenngr{\"o}ßen und deren fl{\"a}chenhafte Heterogenit{\"a}t auf einer homogen hergestellten Fl{\"a}che der Bergbaufolgelandschaft in der Lausitz}, series = {B{\"o}den - eine endliche Ressource, Jahrestagung der Deutschen Bodenkundlichen Gesellschaft, 5. bis 13. September 2009, Bonn}, booktitle = {B{\"o}den - eine endliche Ressource, Jahrestagung der Deutschen Bodenkundlichen Gesellschaft, 5. bis 13. September 2009, Bonn}, publisher = {Deutsche Bodenkundliche Gesellschaft (Selbstverlag)}, address = {Bonn}, language = {de} } @incollection{HuettlFischer, author = {H{\"u}ttl, Reinhard F. and Fischer, Thomas}, title = {Wirkungen auf Boden und Bodenorganismen}, language = {de} } @incollection{FischerBergmannHuettl, author = {Fischer, Thomas and Bergmann, Charlotte and H{\"u}ttl, Reinhard F.}, title = {Auswirkungen sich zeitlich {\"a}ndernder Schadstoffdepositionen auf Prozesse des Kohlenstoff- und Stickstoffumsatzes im Boden}, series = {Atmosph{\"a}rensanierung und Wald{\"o}kosysteme}, booktitle = {Atmosph{\"a}rensanierung und Wald{\"o}kosysteme}, editor = {H{\"u}ttl, Reinhard F. and Bellmann, Klaus and Seiler, Wolfgang}, publisher = {Eberhard-Blottner-Verlag}, address = {Taunusstein}, isbn = {3-89367-053-X}, pages = {144 -- 160}, language = {de} } @misc{JurischkaDinterEfimovaetal., author = {Jurischka, Christoph and Dinter, Franziska and Efimova, Anastasia and Weiss, Romano and Schiebel, Juliane and Schulz, Christian and Fayziev, Bekzodjon and Schierack, Peter and Fischer, Thomas and R{\"o}diger, Stefan}, title = {An explorative study of polymers for 3D printing of bioanalytical test systems}, series = {Clinical Hemorheology and Microcirculation}, volume = {75}, journal = {Clinical Hemorheology and Microcirculation}, number = {1}, issn = {1875-8622}, doi = {10.3233/CH-190713}, pages = {57 -- 84}, abstract = {Background: The 3D printing is relevant as a manufacturing technology of functional models for forensic, pharmaceutical and bioanalytical applications such as drug delivery systems, sample preparation and point-of-care tests. Objective: Melting behavior and autofluorescence of materials are decisive for optimal printing and applicability of the product which are influenced by varying unknown additives. Methods: We have produced devices for bioanalytical applications from commercially available thermoplastic polymers using a melt-layer process. We characterized them by differential scanning calorimetry, fluorescence spectroscopy and functional assays (DNA capture assay, model for cell adhesion, bacterial adhesion and biofilm formation test). Results: From 14 tested colored, transparent and black materials we found only deep black acrylonitrile-butadiene-styrene (ABS) and some black polylactic acid (PLA) useable for fluorescence-based assays, with low autofluorescence only in the short-wave range of 300-400 nm. PLA was suitable for standard bioanalytical purposes due to a glass transition temperature of approximately 60°C, resistance to common laboratory chemicals and easy print processing. For temperature-critical methods, such as hybridization reactions up to 90°C, ABS was better suited. Conclusions: Autofluorescence was not a disadvantage per se but can also be used as a reference signal in assays. The rapid development of individual protocols for sample processing and analysis required the availability of a material with consistent quality over time. For fluorescence-based assays, the use of commercial standard materials did not seem to meet this requirement.}, language = {en} } @misc{FischerVesteEiseleetal., author = {Fischer, Thomas and Veste, Maik and Eisele, Andreas and Bens, Oliver and Spyra, Wolfgang and H{\"u}ttl, Reinhard F.}, title = {Small Scale Spatial Heterogeneity of Normalized Difference Vegetation Indices (NDVI) and Hot Spots of Photosynthesis in Biological Soil Crusts}, series = {Flora}, volume = {207}, journal = {Flora}, number = {3}, doi = {10.1016/j.flora.2012.01.001}, pages = {159 -- 167}, abstract = {Normalized Difference Vegetation Indices (NDVIs) are typically determined using satellite or airborne remote sensing, or field portable spectrometers, which give an averaged signal on centimetre to metre scale plots. Biological soil crust (BSC) patches may have smaller sizes, and ecophysiological, hydrological as well as pedological processes may be heterogeneously distributed within this level of resolution. A ground-based NDVI imaging procedure using low-cost equipment (Olympus Camedia 5000z digital camera equipped with a Hoya R72 infrared filter) was developed in this study to fill this gap at the level of field research, where carrying costly and bulky equipment to remote locations is often the limiting factor for data collection. Method principle and field data are presented, and the field experiment was deepened comparing NDVI measurements and CO2 turnover of soil crust samples in the laboratory, backing the reliability of the approach. A commercially available colour rendition chart with known red (600-700 nm) and NIR (800-900 nm) reflectances was placed into each scene and used for calibration purposes on a per-image basis. Generation of NDVI images involved (i) determination of red and NIR reflectances from the pixel values of the red and NIR channels, respectively, and (ii) calculation and imaging of the NDVI, where NDVI values of -1 to +1 were mapped to grey values of 0 to 255. The correlation between NDVI values retrieved from these images and NDVI values determined using field spectrometry was close (r2 = 0.91), the 95\% confidence interval amounted to 0.10 NDVI units. The pixel resolution was 0.8 mm in the field and 0.2 mm in the laboratory, but can still be improved significantly with closer distance to the crust or with higher camera resolution. NDVI values obtained using the new method were related to the net CO2 uptake of BSCs, where both slope and correlation coefficient of the respective regression function conformed with literature data. Geostatistical analysis revealed that both spatial variability of net CO2 uptake as well as size of individual hot spots of this parameter increased with crust development. The latter never exceeded 4 mm in the investigated crusts, which points to the necessity of high resolution imaging for linking remote sensing with ecophysiology. Perspectively, the new method could be used for field monitoring of both biological soil crusts and vascular vegetation.}, language = {en} } @misc{ZyakunNiiAnnangFrankeetal., author = {Zyakun, Anatoly and Nii-Annang, Seth and Franke, Gabriele and Fischer, Thomas and Buegger, Franz and Dilly, Oliver}, title = {Microbial Actvity and 13C/12C Ratio as Evidence of N-Hexadecane and N-Hexadecanoic Acid Biodegradation in Agricultural and Forest Soils}, series = {Geomicrobiology Journal}, volume = {28}, journal = {Geomicrobiology Journal}, number = {7}, issn = {1521-0529}, doi = {10.1080/01490451.2010.489922}, pages = {632 -- 647}, abstract = {The dynamics of microbial degradation of exogenous contaminants, n-hexadecane and its primary microbial oxidized metabolite, n-hexadecanoic (palmitic) acid, was studied for topsoils, under agricultural management and beech forest on the basis the changes in O2 uptake, CO2 evolution and its associated microbial and non-microbial carbon isotopic signature, the respiratory quotient (RQ) and the priming effect (PE) of substrates. Soil microbial communities in agricultural soil responded to the n-hexadecane addition more rapidly compared to those of forest soil, with lag-periods of about 23 ± 10 and 68 ± 13 hours, respectively. Insignificant difference in the lag-period duration was detected for agricultural (tlag = 30 ± 13 h) and forest (tlag = 30 ± 14 h) soils treated with n-hexadecanoic (palmitic) acid. These results demonstrate that the soil microbiota differed in metabolic activities for using n-hexadecane as a reductive hydrocarbon and n-hexadecanoic acid as a partly oxidized hydrocarbon. The corresponding δ13C of respired CO2 after the addition of the hydrocarbon contaminants to soils indicates a shift in microbial activity towards the consumption of exogenous substrates with a more complete degradation of n-hexadecane in the agricultural soil, for which some initial contents of hydrocarbons are inherent. It was reflected in the carbon isotope signature of microbial biomass. It is supposed that the observed deviation of RQ from theoretically calculated value under microbial substrate mineralization is determined by difference in the time (Δti) of registration of CO2 production and O2 consumption. Positive priming effect (PE) of n-hexadecane and negative PE of n-hexadecanoic (palmitic) acid were detected in agricultural and forest soils. It is suggested that positive PE of n-hexadecane is conditioned by the induction of microbial enzymes that perform hydroxylation/oxygenation of stable SOM compounds mineralized by soil microbiota to CO2. The microbial metabolism coupled with oxidative decarboxylation of n-hexadecanoic acid is considered as one of the most probable causes of the revealed negative PE value.}, language = {en} } @misc{DillyNiiAnnangFrankeetal., author = {Dilly, Oliver and Nii-Annang, Seth and Franke, Gabriele and Fischer, Thomas and Buegger, Franz and Zyakun, Anatoly}, title = {Resilience of microbial respiration, respiratory quotient and stable isotope characteristics to soil hydrocarbon addition}, series = {Soil Biology and Biochemistry}, volume = {43}, journal = {Soil Biology and Biochemistry}, number = {9}, issn = {0038-0717}, doi = {10.1016/j.soilbio.2010.09.026}, pages = {1808 -- 1811}, abstract = {On the basis of CO2 evolution rate, O2 uptake rate, and 13C isotopic signature of respired CO2, the metabolic response to the addition of 13C labelled n-hexadecane and palmitic acid each with supplementary nitrogen was studied for two topsoils, one under continuous agricultural management and the other under beech forest. The CO2 evolution rate was immediately stimulated in the agricultural soil and the respiratory quotient (RQ) decreased from 0.8 to 0.4 mol CO2 evolution rate per mol O2 uptake rate, which was below the theoretically expected value of 0.65 and 0.70 for the degradation of n-hexadecane and palmitic acid, respectively. The microbial response was delayed in the forest soil, but developed better than in the agricultural soil throughout the subsequent 2-4 weeks. Consequently, the respiration rate returned earlier to the initial level for the beech forest soil and the δ13C of respired CO2 and RQ approached values before hydrocarbon addition. Based on the link among respiration rates, RQ and 13C-CO2 value, the added oil-analogue compounds induced a more rapid response in the agricultural soil and were degraded more completely in the forest soil. We concluded that the resilience, which we defined here as the capacity of the soil microbiota to buffer perturbance and to reorganise in response to change resulting in a more desirable system, was higher in our forest soil than for the agricultural soil.}, language = {de} } @misc{FischerKholiavkoSchaafetal., author = {Fischer, Thomas and Kholiavko, Tatiana and Schaaf, Wolfgang and Veste, Maik}, title = {Soil respiration responses of moss and lichen biocoenoses to moderate and severe rain events after summer drought in a temperate early-successional ecosystem}, series = {Ecohydrology}, volume = {16}, journal = {Ecohydrology}, number = {7}, issn = {1936-0592}, doi = {10.1002/eco.2578}, abstract = {It is commonly accepted that CO2 efflux increases with soil water content in aerated soils and that rewetting after periods of soil drying can result in respiration pulses. It has further been shown that soil pores may become water logged which can impede soil gas exchange. The present study aimed to quantify the carbon response of moss (Polytrichum piliferum) and lichen (Cladonia coniocraea) biocoenoses to different quantities of rain in an artificial catchment, which granted that the starting point of the development of both biocoenoses was the same. To address this aim, we conducted in situ soil moisture and soil respiration measurements, where soil respiration was hypothesised to emerge from a cryptogamic vegetation layer and from mineral soil beneath. We found that higher water-holding capacity of the moss layer and higher accumulation of organic matter in the upper mineral soil under mosses result in higher amounts of water stored near the surface. As a consequence, evaporation of water as well as pulses of CO2 efflux after moderate rain following a period of drought were higher in the moss biocoenosis, where the upper mineral soil was of key importance. In contrast, the lichen biocoenosis facilitated penetration of rainwater into the deep soil. Superimposing rewetting pulses, near-saturation of soil pores with water after severe rain resulted in gas exchange inhibition and diminished soil respiration until subsequent aeration in both biocoenoses}, language = {en} } @misc{DuemigVesteHagedornetal., author = {D{\"u}mig, Alexander and Veste, Maik and Hagedorn, Frank and Fischer, Thomas and Lange, Philipp and Spr{\"o}te, Roland and K{\"o}gel-Knabner, Ingrid}, title = {Biological soil crusts on initial soils: organic carbon dynamics and chemistry under temperate climatic conditions}, series = {Biogeosciences Discussion}, volume = {10}, journal = {Biogeosciences Discussion}, number = {1}, issn = {1810-6285}, pages = {851 -- 894}, language = {en} } @inproceedings{SproeteFischerVesteetal., author = {Spr{\"o}te, Roland and Fischer, Thomas and Veste, Maik and Wiehe, Wolfgang and Lange, Philipp and H{\"u}ttl, Reinhard F.}, title = {Development of top soil on quaternary inland dunes - How important are microorganisms?}, series = {Gletscher, Wasser, Mensch - quart{\"a}rer Landschaftswandel im peribaltischen Raum, 35. Hauptversammlung der DEUQUA e.V., 12th Annual Conference of the INQUA PeriBaltic Working Group, 13.-17.9.2010., Greifswald}, booktitle = {Gletscher, Wasser, Mensch - quart{\"a}rer Landschaftswandel im peribaltischen Raum, 35. Hauptversammlung der DEUQUA e.V., 12th Annual Conference of the INQUA PeriBaltic Working Group, 13.-17.9.2010., Greifswald}, publisher = {Lehrstuhl Physische Geographie, Inst. f{\"u}r Geographie und Geologie der Univ. Greifswald}, address = {Greifswald}, pages = {163 -- 164}, language = {en} } @inproceedings{FischerSteinerKrakau, author = {Fischer, Thomas and Steiner, A. and Krakau, U.}, title = {Influence of nitrogen deposition on root mineralization and turnover in two Scots pine (Pinus sylvestris L.) stands in northeastern Germany}, language = {en} } @incollection{BergmannFischerHuettl, author = {Bergmann, Charlotte and Fischer, Thomas and H{\"u}ttl, Reinhard F.}, title = {Decomposition of needle-, herb- and root- litter and Of-layer humus in three scots pine stands}, series = {Changes of atmospheric chemistry and effects on forest ecosystems: A roof experiment without roof.}, booktitle = {Changes of atmospheric chemistry and effects on forest ecosystems: A roof experiment without roof.}, editor = {H{\"u}ttl, Reinhard F. and Bellmann, Klaus}, publisher = {Kluwer Academic Publishers}, address = {Dordrecht}, isbn = {0-7923-5713-2}, pages = {151 -- 176}, language = {en} } @incollection{BergmannFischerHuettl, author = {Bergmann, Charlotte and Fischer, Thomas and H{\"u}ttl, Reinhard F.}, title = {Seasonal variability of organic matter and N input with litterfall in three scots pine stands}, series = {Changes of atmospheric chemistry and effects on forest ecosystems: A roof experiment without roof}, booktitle = {Changes of atmospheric chemistry and effects on forest ecosystems: A roof experiment without roof}, editor = {H{\"u}ttl, Reinhard F. and Bellmann, Klaus}, publisher = {Kluwer Academic Publishers}, address = {Dordrecht}, isbn = {0-7923-5713-2}, pages = {177 -- 186}, language = {en} } @misc{FischerVesteSchaafetal., author = {Fischer, Thomas and Veste, Maik and Schaaf, Wolfgang and D{\"u}mig, Alexander and K{\"o}gel-Knabner, Ingrid and Wiehe, Wolfgang and Bens, Oliver and H{\"u}ttl, Reinhard F.}, title = {Initial pedogenesis in a topsoil crust 3 years after construction of an artificial water catchment in Brandenburg, NE Germany}, series = {Biogeochemistry}, volume = {101}, journal = {Biogeochemistry}, number = {1-3}, issn = {1573-515X}, doi = {10.1007/s10533-010-9464-z}, pages = {165 -- 176}, abstract = {Cyanobacteria and green algae present in biological soil crusts are able to colonize mineral substrates even under extreme environmental conditions. As pioneer organisms, they play a key role during the first phases of habitat colonization. A characteristic crust was sampled 3 years after installation of the artificial water catchment "Chicken creek", thus representing an early successional stage of ecosystem development. Mean annual rainfall and temperature were 559 mm and 9.3°C, respectively. We combined scanning electron microscopy (SEM/EDX) and infrared (FTIR) microscopy to study the contact zone of algal and cyanobacterial mucilage with soil minerals in an undisturbed biological soil crust and in the subjacent sandy substrate. The crust was characterized by an approximately 50 μm thick surface layer, where microorganisms resided and where mineral deposition was trapped, and by an approximately 2.5 mm thick lower crust where mineral particles were stabilized by organo-mineral structures. SEM/EDX microscopy was used to determine the spatial distribution of elements, organic compounds and minerals were identified using FTIR microscopy and X-ray diffraction (XRD). The concentration of organic carbon in the crust was about twice as much as in the parent material. Depletion of Fe, Al and Mn in the lower crust and in the subjacent 5 mm compared to the geological substrate was observed. This could be interpreted as the initial phase of podzolization. Existence of bridging structures between mineral particles of the lower crust, containing phyllosilicates, Fe compounds and organic matter (OM), may indicate the formation of organo-mineral associations. pH decreased from 8.1 in the original substrate to 5.1 on the crust surface 3 years after construction, pointing to rapid weathering of carbonates. Weathering of silicates could not be detected.}, language = {en} } @misc{FischerVesteBensetal., author = {Fischer, Thomas and Veste, Maik and Bens, Oliver and H{\"u}ttl, Reinhard F.}, title = {Dew formation on the surface of biological soil crusts in central European sand ecosystems}, series = {Biogeosciences discussions}, volume = {9}, journal = {Biogeosciences discussions}, doi = {10.5194/bgd-9-8075-2012}, pages = {8075 -- 8092}, abstract = {Dew formation was investigated in three developmental stages of biological soil crusts (BSC), which were collected along a catena of an inland dune and in the initial substrate. The Penman equation, which was developed for saturated surfaces, was modified for unsaturated surfaces and used for prediction of dewfall rates. The levels of surface saturation required for this approach were predicted using the water retention functions and the thicknesses of the BSCs. During a single event, dewfall increased with crust development from 0.08 kg m-2 for the initial substrate to 0.10, 0.20 and 0.25 kg m-2 for crusts stages 1 to 3, respectively, which was well reflected by the model response. The suggested mechanism of dew formation involves a delay in water saturation in near-surface soil pores and EPS where the crusts were thicker and where the water capacity was high, resulting in elevated vapor flux towards the surface. The results also indicate that the amount of dewfall was too low to observe water flow into deeper soil. Analysis of the soil water retention curves revealed that, despite the sandy mineral matrix, moist crusts with clogged by swollen EPS pores exhibited a clay-like behavior. It is hypothesized that BSCs gain double benefit from suppressing their competitors by runoff generation and from improving their water supply by dew collection. Despite higher amounts of dew, the water availability to the crust community decreases with crust development, which may be compensated by ecophysiological adaptation of crust organisms, and which may further suppress higher vegetation or mosses.}, language = {en} } @misc{HuettlFischer, author = {H{\"u}ttl, Reinhard F. and Fischer, Thomas}, title = {Carbon sequestration and landscape ecology in Western Europe - editorial}, series = {Ecological Engineering}, volume = {29}, journal = {Ecological Engineering}, number = {4}, issn = {0925-8574}, doi = {10.1016/j.ecoleng.2006.10.001}, pages = {317 -- 318}, language = {en} } @misc{DuemigVesteHagedornetal., author = {D{\"u}mig, Alexander and Veste, Maik and Hagedorn, Frank and Fischer, Thomas and Lange, Philipp and Spr{\"o}te, Roland and K{\"o}gel-Knabner, Ingrid}, title = {Organic matter from biological soil crusts induces the initial formation of sandy temperate soils}, series = {Catena}, volume = {122}, journal = {Catena}, doi = {10.1016/j.catena.2014.06.011}, pages = {196 -- 208}, abstract = {Different development stages of algae-dominated and moss-dominated biological soil crusts (BSCs) were sampled on a natural sand dune (b17 years old) and on an experimental sand dune (b8 years old) along a catena, including gradients of vegetation cover, location on the slope, as well as composition and thickness of BSC organisms in northeastern Germany. The accumulation of BSC-derived organic carbon (OC)was determined for bulk materials and fractions less than 63 μm. The OC composition was characterized by solid-state 13C NMR spectroscopy and the carbohydrate-C signature. 14C contents were determined to assess the origin and dynamics of OC. From the radiocarbon contents, two OC pools were differentiated: recent BSC-derived and lignite-derived "old" OC. Downward movement of OC into the underlying substratewas found only undermoss-dominated BSCs at the old sand dune. BSC-derived OC was mainly composed of carbohydrate-C and, to a lesser extent, alkyl C and N-alkyl C, with considerably higher contributions of alkyl C in the young dune, indicating differences in the composition of extracellular polymeric substances produced by the BSCs with age. This is consistent with higher proportions of water-soluble OC of moss-dominated BSCs at the old dune, which is leached in the underlying substrate and initiates soil formation. Because of the channeling effect of mosses, OC depth translocation along with suspended colloidal substances contribute to OC accumulation in substrates.}, language = {en} } @misc{FischerGypserSubbotinaetal., author = {Fischer, Thomas and Gypser, Stella and Subbotina, Maria and Veste, Maik}, title = {Synergic hydraulic and nutritional feedback mechanisms control surface patchiness of biological soil crusts on tertiary sands at a post-mining site}, series = {Journal of Hydrology and Hydromechanics}, volume = {62}, journal = {Journal of Hydrology and Hydromechanics}, number = {4}, issn = {0042-790X}, doi = {10.2478/johh-2014-0038}, pages = {293 -- 302}, abstract = {In a recultivation area located in Brandenburg, Germany, five types of biocrusts (initial BSC1, developed BSC2 and BSC3, mosses, lichens) and non-crusted mineral substrate were sampled on tertiary sand deposited in 1985- 1986 to investigate hydrologic interactions between crust patches. Crust biomass was lowest in the non-crusted substrate, increased to the initial BSC1 and peaked in the developed BSC2, BSC3, the lichens and the mosses. Water infiltration was highest on the substrate, and decreased to BSC2, BSC1 and BSC3. Non-metric multidimensional scaling revealed that the lichens and BSC3 were associated with water soluble nutrients and with pyrite weathering products, thus representing a high nutrient low hydraulic feedback mode. The mosses and BSC2 represented a low nutrient high hydraulic feedback mode. These feedback mechanisms were considered as synergic, consisting of run-off generating (low hydraulic) and run-on receiving (high hydraulic) BSC patches. Three scenarios for BSC succession were proposed. (1) Initial BSCs sealed the surface until they reached a successional stage (represented by BSC1) from which the development into either of the feedback modes was triggered, (2) initial heterogeneities of the mineral substrate controlled the development of the feedback mode, and (3) complex interactions between lichens and mosses occurred at later stages of system development.}, language = {en} } @misc{GypserVesteFischeretal., author = {Gypser, Stella and Veste, Maik and Fischer, Thomas and Lange, Philipp}, title = {Infiltration and water retention of biological soil crusts on reclaimed soils of former open-cast lignite mining sites in Brandenburg, north-east Germany}, series = {Journal of hydrology and hydromechanics}, volume = {64}, journal = {Journal of hydrology and hydromechanics}, number = {1}, doi = {10.1515/johh-2016-0009}, pages = {1 -- 11}, abstract = {Investigations were done on two former open-cast lignite mining sites under reclamation, an artificial sand dune in Welzow S{\"u}d, and a forest plantation in Schlabendorf S{\"u}d (Brandenburg, Germany). The aim was to associate the topsoil hydrological characteristics of green algae dominated as well as moss and soil lichen dominated biological soil crusts during crustal succession with their water retention and the repellency index on sandy soils under temperate cli-mate and different reliefs. The investigation of the repellency index showed on the one hand an increase due to the cross-linking of sand parti-cles by green algae which resulted in clogging of pores. On the other hand, the occurrence of moss plants led to a de-crease of the repellency index due to absorption caused by bryophytes. The determination of the water retention curves showed an increase of the water holding capacity, especially in conjunction with the growth of green algae layer. The pore-related van Genuchten parameter indicate a clay-like behaviour of the developed soil crusts. Because of the inho-mogeneous distribution of lichens and mosses as well as the varying thickness of green algae layers, the water retention differed between the study sites and between samples of similar developmental stages. However, similar tendencies of water retention and water repellency related to the soil crust formation were observed. Biological soil crusts should be considered after disturbances in the context of reclamation measures, because the ini-tial development of green algae biocrusts lead to an increasing repellency index, while the occurrence of mosses and a gain in organic matter enhance the water holding capacity. Thus, the succession of biocrusts and their small-scale succes-sion promote the development of soil and ecosystem.}, language = {en} } @misc{GypserHerppichFischeretal., author = {Gypser, Stella and Herppich, Werner B. and Fischer, Thomas and Lange, Philipp and Veste, Maik}, title = {Photosynthetic characteristics and their spatial variance on biological soil crusts covering initial soils of post-mining sites in Lower Lusatia, NE Germany}, series = {Flora}, volume = {Vol. 220}, journal = {Flora}, issn = {0367-2530}, doi = {10.1016/j.flora.2016.02.012}, pages = {103 -- 116}, abstract = {Following surface disturbance, quaternary sands are the basic substrate for soil development in the Lusatian reclamation area. These substrates mostly contain few organic matter and, hence, are nutrient poor. Accumulation of soil carbon is an important factor for ecosystem development, where biological soil crusts initially influence soil processes and promote ecosystem succession. The compositional structures of biological soil crusts at various developmental stages and their photosynthetic properties were investigated on two former open-cast lignite sites, currently under reclamation, an artificial sand dune in Welzow S{\"u}d, and a forest plantation in Schlabendorf S{\"u}d (Brandenburg, Germany). As development of biological soil crusts progressed, their contents of organic carbon and total chlorophyll increased. The ratio of these parameters, however, varied with the relative contribution of lichens and mosses in particular. Also maximum photochemical efficiency, net photosynthesis and respiration increased with crustal development. An additional evaluation of NDVI and chlorophyll fluorescence images showed that especially moss-dominated biocrusts had higher photosynthetic capacity compared to green algae-dominated biocrusts or soil lichens, so the photosynthetic capacity showed to be highly species-specific. The ratio of gross photosynthesis to respiration indicated a higher ecological efficiency of biocrusts dominated by green algae than of lichen-dominated biocrusts. The occurrence of soil lichens reduced net CO2 fixation and increased CO2 release due to the enhanced mycobiontic respiration. During crustal succession, the rise of photosynthesis-related parameters is not necessarily linear as a result of the highly heterogenic distribution of the different crustal organisms between biocrusts of similar developmental stages as well as between those growing at the two study sites. Therefore, the evaluation of relevant ecophysiological parameters highlighted that not all biocrust-forming organisms similarly contribute to the ecophysiological behavior of biological soil crusts. Nevertheless, the occurrence of the biological soil crusts promoted soil formation and accumulation of soil carbon in initial soils.}, language = {en} } @misc{GypserVesteFischeretal., author = {Gypser, Stella and Veste, Maik and Fischer, Thomas and Lange, Philipp}, title = {Formation of soil lichen crusts at reclaimed post-mining sites, Lower Lusatia, North-east Germany}, series = {Graphis Scripta}, volume = {27}, journal = {Graphis Scripta}, number = {1-2}, issn = {0901-7593}, pages = {3 -- 14}, abstract = {Biological soil crusts were investigated at reclaimed post-mining sites near Welzow and Schlabendorf in Lower Lusatia (Brandenburg, Germany). Various development stages from initial biological soil crusts built up by green algae, to more developed soil crusts with mosses, as well as moss-soil lichen crusts, were classified. The spatial-temporal dynamics during the development resulted in a moss-lichens cover with discrete patches of pioneer organisms like green algae in between. At the study sites, 13 species of terricolous lichens were identified. The formation of the biological soil crust is important for the accumulation of soil organic matter in the first millimeters of the topsoil of these pioneer ecosystems. A correlation between cryptogamic biomass and soil carbon content were found.}, language = {en} } @misc{FischerVeste, author = {Fischer, Thomas and Veste, Maik}, title = {Carbon cycling of biological soil crusts mirrors ecological maturity along a Central European inland dune catena}, series = {Catena}, volume = {160}, journal = {Catena}, issn = {0341-8162}, doi = {10.1016/j.catena.2017.09.004}, pages = {68 -- 75}, abstract = {Photosynthesis and respiration of biological soil crusts (BSCs) sampled along a mobile inland dune catena were determined to evaluate the applicability of Odum's P/R ratio, determined under controlled conditions, for estimation of ecosystem maturity. The theory is that in the early stages of ecological succession, the total photosynthesis (P) exceeds the rate of community respiration (R), so that the P/R ratio is greater than 1, and that P/R approaches 1 as succession occurs. In the special case of organic pollution, the P/R ratio is typically less than 1. Samples were collected in the deflation zone of the dune near the crest (BSC1, thickness 2-3 mm), at the lee side of grass tussocks at the slope (BSC2, thickness 2-4 mm) and near the base (BSC3, thickness 4-6 mm). Non crusted sand was used as control (BSC0). Photosynthesis, respiration, crust biomass, as well as fossil and allochthonous pedogenic carbon entering the system with mineral substrate were determined. The respiration of the BSC1 was dominated by the degradation of allochthonous organic matter, leading to a diminished P/R ratio. The better developed BSC2 and BSC3 were less influenced by allochthonous organic matter, where BSC maturity increased downslope with biomass increase. No significant relation between the P/R ratio and soil water tension was found. Crust carbon pools increased and flows intensified, but mineralization constants decreased with system maturation. It was concluded that Odum's P/R ratio and accumulation of recalcitrant to biodegradation organic matter are indicative for biocrust maturity.}, language = {en} } @inproceedings{GypserFischerLangeetal., author = {Gypser, Stella and Fischer, Thomas and Lange, Philipp and Veste, Maik}, title = {Impact of biocrust succession on water retention and repellency on open-cast lignite mining sites under reclamation in Lower Lusatia, NE-Germany}, series = {European Geosciences Union, General Assembly 2016, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2016, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {Mining activities can strongly affect ecosystem properties by destruction of naturally developed soils and removal of vegetation. The unstructured substrates show high bulk densities, compaction, low water infiltration rates, reduced water holding capacities and higher susceptibility to wind and water erosion. In the initial stage of the ecosystem development, the post-mining sites are open areas without or with a low cover of higher vegetation. It is well-known that biocrusts are able to colonize the soil surface under such extreme conditions without human support and affect soil hydrological processes such as water infiltration, run-off or re-distribution. Investigations were conducted on two former lignite open-cast mining sites, an artificial sand dune on the reclaimed watershedWelzow "Neuer Lugteich" and a reforestation area in Schlabendorf (Brandenburg, north-east Germany). The aim was to relate the hydrological characteristics of the topsoil to successional stages of biological soil crusts on reclaimed soils and their influence on repellency index and water holding capacity compared to pure mining substrate. Our study emphasized the influence of changing successional stages and species composition of biological soil crusts, forming a small-scale crust pattern, on water repellency and retention on sandy soils in temperate climate. Different successional stages of soil crusts were identified from initial scattered green algae crusts, dominated by Zygogonium spec. and Ulothrix spec., and more developed soil crusts containing mosses such as Ceratodon purpureus and Polytrichum piliferum. Lichens of the Genus Cladonia were more pronouncedly contributed to biocrusts at later and mature stages of development. The repellency index on the one hand increased due to the cross-linking of sand particles by the filamentous green algae Zygogonium spec. which resulted in clogging of pores, and on the other hand decreased with the occurrence of moss plants due to absorption caused by bryophytes. The determination of the water retention curves showed an increase of the water holding capacity, especially in conjunction with the growth of green algae layer. The absorption capacity of soil crust biota as well as a decreased pore diameter in the green algae layers positively affected the water retention of crusted soil compared to pure substrate. The occurrence of bryophytes with later succession weakened the repellent behavior of the biocrusts, increased infiltration, and might have affected the run-off at small-scale on biocrusts. Certainly, the biological soil crusts showed water repellent properties but no distinctive hydrophobic characteristics. On both locations, similar trends of water repellency and retention related to crustal formation were observed, in spite of different relief, reclamation time and inhomogeneous distribution of crustal organisms.}, language = {en} } @incollection{KoegelKnabnerBensHuettletal., author = {K{\"o}gel-Knabner, Ingrid and Bens, Oliver and H{\"u}ttl, Reinhard F. and Fischer, Thomas and D{\"u}mig, Alexander and Spr{\"o}te, Roland}, title = {Project A3 - Initial stages of humus development}, series = {Structures and processes of the initial ecosystem development phase in an artificial water catchment (Final report CRC/TR 38)}, booktitle = {Structures and processes of the initial ecosystem development phase in an artificial water catchment (Final report CRC/TR 38)}, editor = {H{\"u}ttl, Reinhard F. and K{\"o}gel-Knabner, Ingrid and Schulin, Rainer and Gerwin, Werner}, publisher = {BTU Forschungszentrum Landschaftsentwicklung und Bergbaulandschaften (FZLB)}, address = {Cottbus}, pages = {25 -- 35}, language = {en} } @inproceedings{FischerSchneiderBaumannetal., author = {Fischer, Thomas and Schneider, Bernd Uwe and Baumann, Karen and H{\"u}ttl, Reinhard F.}, title = {Spatial Distribution of Black pine (Pinus nigra L.) roots and its relationship to chemical properties of bulk and rhizosphere soil equilibrium solution}, series = {Woody Root Processes: Revealing the Hidden Half : Sade Boqer, Israel, 4-6 February 2006}, booktitle = {Woody Root Processes: Revealing the Hidden Half : Sade Boqer, Israel, 4-6 February 2006}, language = {en} }